Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
We are all familiar with this reaction now, for it is acetylene that
gives the dazzling light of the automobiles and of the automatic signal
buoys of the seacoast. When burned with pure oxygen instead of air it
gives the hottest of chemical flames, hotter even than the oxy-hydrogen
blowpipe. For although a given weight of hydrogen will give off more
heat when it burns than carbon will, yet acetylene will give off more
heat than either of its elements or both of them when they are separate.
This is because acetylene has stored up heat in its formation instead of
giving it off as in most reactions, or to put it in chemical language,
acetylene is an endothermic compound. It has required energy to bring
the H and the C together, therefore it does not require energy to
separate them, but, on the contrary, energy is released when they are
separated. That is to say, acetylene is explosive not only when mixed
with air as coal gas is but by itself. Under a suitable impulse
acetylene will break up into its original carbon and hydrogen with great
violence. It explodes with twice as much force without air as ordinary
coal gas with air. It forms an explosive compound with copper, so it has
to be kept out of contact with brass tubes and stopcocks. But compressed
in steel cylinders and dissolved in acetone, it is safe and commonly
used for welding and melting. It is a marvelous though not an unusual
sight on city streets to see a man with blue glasses on cutting down
through a steel rail with an oxy-acetylene blowpipe as easily as a
carpenter saws off a board. With such a flame he can carve out a pattern
in a steel plate in a way that reminds me of the days when I used to
make brackets with a scroll saw out of cigar boxes. The torch will
travel through a steel plate an inch or two thick at a rate of six to
ten inches a minute.
[Illustration: Courtesy of the Carborundum Company, Niagara Falls
MAKING ALOXITE IN THE ELECTRIC FURNACES BY FUSING COKE AND BAUXITE
In the background are the circular furnaces. In the foreground are the
fused masses of the product]
[Illustration: Courtesy of the Carborundum Co., Niagara Falls
A BLOCK OF CARBORUNDUM CRYSTALS]
[Illustration: Courtesy of the Carborundum Co., Niagara Falls
MAKING CARBORUNDUM IN THE ELECTRIC FURNACE
At the end may be seen the attachments for the wires carrying the
electric current and on the side the flames from the burning carbon.]
The temperatures attainable with various fuels in the compound blowpipe
are said to be:
Acetylene with oxygen 7878 deg. F.
Hydrogen with oxygen 6785 deg. F.
Coal gas with oxygen 6575 deg. F.
Gasoline with oxygen 5788 deg. F.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account