Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
If we compare the formula of acetylene, C_{2}H_{2} with that of
ethylene, C_{2}H_{4}, or with ethane, C_{2}H_{6}, we see that acetylene
could take on two or four more atoms. It is evidently what the chemists
call an "unsaturated" compound, one that has not reached its limit of
hydrogenation. It is therefore a very active and energetic compound,
ready to pick up on the slightest instigation hydrogen or oxygen or
chlorine or any other elements that happen to be handy. This is why it
is so useful as a starting point for synthetic chemistry.
To build up from this simple substance, acetylene, the higher compounds
of carbon and oxygen it is necessary to call in the aid of that
mysterious agency, the catalyst. Acetylene is not always acted upon by
water, as we know, for we see it bubbling up through the water when
prepared from the carbide. But if to the water be added a little acid
and a mercury salt, the acetylene gas will unite with the water forming
a new compound, acetaldehyde. We can show the change most simply in this
fashion:
C_{2}H_{2} + H_{2}O --> C_{2}H_{4}O
acetylene _added to_ water _forms_ acetaldehyde
Acetaldehyde is not of much importance in itself, but is useful as a
transition. If its vapor mixed with hydrogen is passed over finely
divided nickel, serving as a catalyst, the two unite and we have
alcohol, according to this reaction:
C_{2}H_{4}O + H_{2} --> C_{2}H_{6}O
acetaldehyde _added to_ hydrogen _forms_ alcohol
Alcohol we are all familiar with--some of us too familiar, but the
prohibition laws will correct that. The point to be noted is that the
alcohol we have made from such unpromising materials as limestone and
coal is exactly the same alcohol as is obtained by the fermentation of
fruits and grains by the yeast plant as in wine and beer. It is not a
substitute or imitation. It is not the wood spirits (methyl alcohol,
CH_{4}O), produced by the destructive distillation of wood, equally
serviceable as a solvent or fuel, but undrinkable and poisonous.
Now, as we all know, cider and wine when exposed to the air gradually
turn into vinegar, that is, by the growth of bacteria the alcohol is
oxidized to acetic acid. We can, if we like, dispense with the bacteria
and speed up the process by employing a catalyst. Acetaldehyde, which is
halfway between alcohol and acid, may also be easily oxidized to acetic
acid. The relationship is readily seen by this:
C{2}H_{6}O --> CC_{2}H_{4}O --> C_{2}H_{4}O_{3}
alcohol acetaldehyde acetic acid
Public-domain text, read in full here on John Shaqi.
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