Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Acetic acid, familiar to us in a diluted and flavored form as vinegar,
is when concentrated of great value in industry, especially as a
solvent. I have already referred to its use in combination with
cellulose as a "dope" for varnishing airplane canvas or making
non-inflammable film for motion pictures. Its combination with lime,
calcium acetate, when heated gives acetone, which, as may be seen from
its formula (C_{3}H_{6}O) is closely related to the other compounds we
have been considering, but it is neither an alcohol nor an acid. It is
extensively employed as a solvent.
Acetone is not only useful for dissolving solids but it will under
pressure dissolve many times its volume of gaseous acetylene. This is a
convenient way of transporting and handling acetylene for lighting or
welding.
If instead of simply mixing the acetone and acetylene in a solution we
combine them chemically we can get isoprene, which is the mother
substance of ordinary India rubber. From acetone also is made the "war
rubber" of the Germans (methyl rubber), which I have mentioned in a
previous chapter. The Germans had been getting about half their supply
of acetone from American acetate of lime and this was of course shut
off. That which was produced in Germany by the distillation of beech
wood was not even enough for the high explosives needed at the front. So
the Germans resorted to rotting potatoes--or rather let us say, since it
sounds better--to the cultivation of _Bacillus macerans_. This
particular bacillus converts the starch of the potato into two-thirds
alcohol and one-third acetone. But soon potatoes got too scarce to be
used up in this fashion, so the Germans turned to calcium carbide as a
source of acetone and before the war ended they had a factory capable of
manufacturing 2000 tons of methyl rubber a year. This shows the
advantage of having several strings to a bow.
The reason why acetylene is such an active and acquisitive thing the
chemist explains, or rather expresses, by picturing its structure in
this shape:
H-C[triple bond]C-H
Now the carbon atoms are holding each other's hands because they have
nothing else to do. There are no other elements around to hitch on to.
But the two carbons of acetylene readily loosen up and keeping the
connection between them by a single bond reach out in this fashion with
their two disengaged arms and grab whatever alien atoms happen to be in
the vicinity:
| |
H-C-C-H
| |
Carbon atoms belong to the quadrumani like the monkeys, so they are
peculiarly fitted to forming chains and rings. This accounts for the
variety and complexity of the carbon compounds.
Public-domain text, read in full here on John Shaqi.
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