Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
But the electrical furnace could not be used on a commercial scale until
the dynamo replaced the battery as a source of electricity. The
industrial development of the electrical furnace centered about the
search for a cheap method of preparing aluminum. This is the metallic
base of clay and therefore is common enough. But clay, as we know from
its use in making porcelain, is very infusible and difficult to
decompose. Sixty years ago aluminum was priced at $140 a pound, but one
would have had difficulty in buying such a large quantity as a pound at
any price. At international expositions a small bar of it might be seen
in a case labeled "silver from clay." Mechanics were anxious to get the
new metal, for it was light and untarnishable, but the metallurgists
could not furnish it to them at a low enough price. In order to extract
it from clay a more active metal, sodium, was essential. But sodium also
was rare and expensive. In those days a professor of chemistry used to
keep a little stick of it in a bottle under kerosene and once a year he
whittled off a piece the size of a pea and threw it into water to show
the class how it sizzled and gave off hydrogen. The way to get cheaper
aluminum was, it seemed, to get cheaper sodium and Hamilton Young
Castner set himself at this problem. He was a Brooklyn boy, a student of
Chandler's at Columbia. You can see the bronze tablet in his honor at
the entrance of Havemeyer Hall. In 1886 he produced metallic sodium by
mixing caustic soda with iron and charcoal in an iron pot and heating in
a gas furnace. Before this experiment sodium sold at $2 a pound; after
it sodium sold at twenty cents a pound.
But although Castner had succeeded in his experiment he was defeated in
his object. For while he was perfecting the sodium process for making
aluminum the electrolytic process for getting aluminum directly was
discovered in Oberlin. So the $250,000 plant of the "Aluminium Company
Ltd." that Castner had got erected at Birmingham, England, did not make
aluminum at all, but produced sodium for other purposes instead. Castner
then turned his attention to the electrolytic method of producing sodium
by the use of the power of Niagara Falls, electric power. Here in 1894
he succeeded in separating common salt into its component elements,
chlorine and sodium, by passing the electric current through brine and
collecting the sodium in the mercury floor of the cell. The sodium by
the action of water goes into caustic soda. Nowadays sodium and chlorine
and their components are made in enormous quantities by the
decomposition of salt. The United States Government in 1918 procured
nearly 4,000,000 pounds of chlorine for gas warfare.
Public-domain text, read in full here on John Shaqi.
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