Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
The discovery of the electrical process of making aluminum that
displaced the sodium method was due to Charles M. Hall. He was the son
of a Congregational minister and as a boy took a fancy to chemistry
through happening upon an old text-book of that science in his father's
library. He never knew who the author was, for the cover and title page
had been torn off. The obstacle in the way of the electrolytic
production of aluminum was, as I have said, because its compounds were
so hard to melt that the current could not pass through. In 1886, when
Hall was twenty-two, he solved the problem in the laboratory of Oberlin
College with no other apparatus than a small crucible, a gasoline burner
to heat it with and a galvanic battery to supply the electricity. He
found that a Greenland mineral, known as cryolite (a double fluoride of
sodium and aluminum), was readily fused and would dissolve alumina
(aluminum oxide). When an electric current was passed through the melted
mass the metal aluminum would collect at one of the poles.
In working out the process and defending his claims Hall used up all his
own money, his brother's and his uncle's, but he won out in the end and
Judge Taft held that his patent had priority over the French claim of
Herault. On his death, a few years ago, Hall left his large fortune to
his Alma Mater, Oberlin.
Two other young men from Ohio, Alfred and Eugene Cowles, with whom Hall
was for a time associated, wore the first to develop the wide
possibilities of the electric furnace on a commercial scale. In 1885
they started the Cowles Electric Smelting and Aluminum Company at
Lockport, New York, using Niagara power. The various aluminum bronzes
made by absorbing the electrolyzed aluminum in copper attracted
immediate attention by their beauty and usefulness in electrical work
and later the company turned out other products besides aluminum, such
as calcium carbide, phosphorus, and carborundum. They got carborundum as
early as 1885 but miscalled it "crystallized silicon," so its
introduction was left to E.A. Acheson, who was a graduate of Edison's
laboratory. In 1891 he packed clay and charcoal into an iron bowl,
connected it to a dynamo and stuck into the mixture an electric light
carbon connected to the other pole of the dynamo. When he pulled out the
rod he found its end encrusted with glittering crystals of an unknown
substance. They were blue and black and iridescent, exceedingly hard and
very beautiful. He sold them at first by the carat at a rate that would
amount to $560 a pound. They were as well worth buying as diamond dust,
but those who purchased them must have regretted it, for much finer
crystals were soon on sale at ten cents a pound. The mysterious
substance turned out to be a compound of carbon and silicon, the
simplest possible compound, one atom of each, CSi. Acheson set up a
factory at Niagara, where he made it in ten-ton batches. The furnace
Public-domain text, read in full here on John Shaqi.
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