Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Silicon is next to oxygen the commonest element in the world. It forms a
quarter of the earth's crust, yet it is unfamiliar to most of us. That
is because it is always found combined with oxygen in the form of silica
as quartz crystal or sand. This used to be considered too refractory to
be blown but is found to be easily manipulable at the high temperatures
now at the command of the glass-blower. So the chemist rejoices in
flasks that he can heat red hot in the Bunsen burner and then plunge
into ice water without breaking, and the cook can bake and serve in a
dish of "pyrex," which is 80 per cent. silica.
At the beginning of the twentieth century minute specimens of silicon
were sold as laboratory curiosities at the price of $100 an ounce. Two
years later it was turned out by the barrelful at Niagara as an
accidental by-product and could not find a market at ten cents a pound.
Silicon from the electric furnace appears in the form of hard,
glittering metallic crystals.
An alloy of iron and silicon, ferro-silicon, made by heating a mixture
of iron ore, sand and coke in the electrical furnace, is used as a
deoxidizing agent in the manufacture of steel.
Since silicon has been robbed with difficulty of its oxygen it takes it
on again with great avidity. This has been made use of in the making of
hydrogen. A mixture of silicon (or of the ferro-silicon alloy containing
90 per cent. of silicon) with soda and slaked lime is inert, compact and
can be transported to any point where hydrogen is needed, say at a
battle front. Then the "hydrogenite," as the mixture is named, is
ignited by a hot iron ball and goes off like thermit with the production
of great heat and the evolution of a vast volume of hydrogen gas. Or the
ferro-silicon may be simply burned in an atmosphere of steam in a closed
tank after ignition with a pinch of gunpowder. The iron and the silicon
revert to their oxides while the hydrogen of the water is set free. The
French "silikol" method consists in treating silicon with a 40 per cent.
solution of soda.
Another source of hydrogen originating with the electric furnace is
"hydrolith," which consists of calcium hydride. Metallic calcium is
prepared from lime in the electric furnace. Then pieces of the calcium
are spread out in an oven heated by electricity and a current of dry
hydrogen passed through. The gas is absorbed by the metal, forming the
hydride (CaH_{2}). This is packed up in cans and when hydrogen is
desired it is simply dropped into water, when it gives off the gas just
as calcium carbide gives off acetylene.
This last reaction was also used in Germany for filling Zeppelins. For
calcium carbide is convenient and portable and acetylene, when it is
once started, as by an electric shock, decomposes spontaneously by its
own internal heat into hydrogen and carbon. The latter is left as a
fine, pure lampblack, suitable for printer's ink.
Public-domain text, read in full here on John Shaqi.
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