Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Before the introduction of the artificial abrasives fine grinding was
mostly done by emery, which is an impure form of aluminum oxide found in
nature. A purer form is made from the mineral bauxite by driving off its
combined water. Bauxite is the ore from which is made the pure aluminum
oxide used in the electric furnace for the production of metallic
aluminum. Formerly we imported a large part of our bauxite from France,
but when the war shut off this source we developed our domestic fields
in Arkansas, Alabama and Georgia, and these are now producing half a
million tons a year. Bauxite simply fused in the electric furnace makes
a better abrasive than the natural emery or corundum, and it is sold for
this purpose under the name of "aloxite," "alundum," "exolon," "lionite"
or "coralox." When the fused bauxite is worked up with a bonding
material into crucibles or muffles and baked in a kiln it forms the
alundum refractory ware. Since alundum is porous and not attacked by
acids it is used for filtering hot and corrosive liquids that would eat
up filter-paper. Carborundum or crystolon is also made up into
refractory ware for high temperature work. When the fused mass of the
carborundum furnace is broken up there is found surrounding the
carborundum core a similar substance though not quite so hard and
infusible, known as "carborundum sand" or "siloxicon." This is mixed
with fireclay and used for furnace linings.
Many new forms of refractories have come into use to meet the demands of
the new high temperature work. The essentials are that it should not
melt or crumble at high heat and should not expand and contract greatly
under changes of temperature (low coefficient of thermal expansion).
Whether it is desirable that it should heat through readily or slowly
(coefficient of thermal conductivity) depends on whether it is wanted as
a crucible or as a furnace lining. Lime (calcium oxide) fuses only at
the highest heat of the electric furnace, but it breaks down into dust.
Magnesia (magnesium oxide) is better and is most extensively employed.
For every ton of steel produced five pounds of magnesite is needed.
Formerly we imported 90 per cent. of our supply from Austria, but now we
get it from California and Washington. In 1913 the American production
of magnesite was only 9600 tons. In 1918 it was 225,000. Zirconia
(zirconium oxide) is still more refractory and in spite of its greater
cost zirkite is coming into use as a lining for electric furnaces.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account