Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
3. Gray cast iron; carbon as graphite (enlarged 500 times)
4. Steel composed of cementite (white) and pearlite (black) (enlarged 50
times)]
Another way of protecting iron ware from rusting is to rust it. This is
a sort of prophylactic method like that adopted by modern medicine where
inoculation with a mild culture prevents a serious attack of the
disease. The action of air and water on iron forms a series of compounds
and mixtures of them. Those that contain least oxygen are hard, black
and magnetic like iron itself. Those that have most oxygen are red and
yellow powders. By putting on a tight coating of the black oxide we can
prevent or hinder the oxidation from going on into the pulverulent
stage. This is done in several ways. In the Bower-Barff process the
articles to be treated are put into a closed retort and a current of
superheated steam passed through for twenty minutes followed by a
current of producer gas (carbon monoxide), to reduce any higher oxides
that may have been formed. In the Gesner process a current of gasoline
vapor is used as the reducing agent. The blueing of watch hands, buckles
and the like may be done by dipping them into an oxidizing bath such as
melted saltpeter. But in order to afford complete protection the layer
of black oxide must be thickened by repeating the process which adds to
the time and expense. This causes a slight enlargement and the high
temperature often warps the ware so it is not suitable for nicely
adjusted parts of machinery and of course tools would lose their temper
by the heat.
A new method of rust proofing which is free from these disadvantages is
the phosphate process invented by Thomas Watts Coslett, an English
chemist, in 1907, and developed in America by the Parker Company of
Detroit. This consists simply in dipping the sheet iron or articles into
a tank filled with a dilute solution of iron phosphate heated nearly to
the boiling point by steam pipes. Bubbles of hydrogen stream off rapidly
at first, then slower, and at the end of half an hour or longer the
action ceases, and the process is complete. What has happened is that
the iron has been converted into a basic iron phosphate to a depth
depending upon the density of articles processed. Any one who has
studied elementary qualitative analysis will remember that when he added
ammonia to his "unknown" solution, iron and phosphoric acid, if present,
were precipitated together, or in other words, iron phosphate is
insoluble except in acids. Therefore a superficial film of such
phosphate will protect the iron underneath except from acids. This film
is not a coating added on the outside like paint and enamel or tin and
nickel plate. It is therefore not apt to scale off and it does not
increase the size of the article. No high heat is required as in the
Sherardizing and Bower-Barff processes, so steel tools can be treated
without losing their temper or edge.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account