Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
The deposit consisting of ferrous and ferric phosphates mixed with black
iron oxide may be varied in composition, texture and color. It is
ordinarily a dull gray and oiling gives a soft mat black more in
accordance with modern taste than the shiny nickel plating that
delighted our fathers. Even the military nowadays show more quiet taste
than formerly and have abandoned their glittering accoutrements.
The phosphate bath is not expensive and can be used continuously for
months by adding more of the concentrated solution to keep up the
strength and removing the sludge that is precipitated. Besides the iron
the solution contains the phosphates of other metals such as calcium or
strontium, manganese, molybdenum, or tungsten, according to the
particular purpose. Since the phosphating solution does not act on
nickel it may be used on articles that have been partly nickel-plated so
there may be produced, for instance, a bright raised design against a
dull black background. Then, too, the surface left by the Parker process
is finely etched so it affords a good attachment for paint or enamel if
further protection is needed. Even if the enamel does crack, the iron
beneath is not so apt to rust and scale off the coating.
These, then, are some of the methods which are now being used to combat
our eternal enemy, the rust that doth corrupt. All of them are useful in
their several ways. No one of them is best for all purposes. The claim
of "rust-proof" is no more to be taken seriously than "fire-proof." We
should rather, if we were finical, have to speak of "rust-resisting"
coatings as we do of "slow-burning" buildings. Nature is insidious and
unceasing in her efforts to bring to ruin the achievements of mankind
and we need all the weapons we can find to frustrate her destructive
determination.
But it is not enough for us to make iron superficially resistant to rust
from the atmosphere. We should like also to make it so that it would
withstand corrosion by acids, then it could be used in place of the
large and expensive platinum or porcelain evaporating pans and similar
utensils employed in chemical works. This requirement also has been met
in the non-corrosive forms of iron, which have come into use within the
last five years. One of these, "tantiron," invented by a British
metallurgist, Robert N. Lennox, in 1912, contains 15 per cent. of
silicon. Similar products are known as "duriron" and "Buflokast" in
America, "metilure" in France, "ileanite" in Italy and "neutraleisen" in
Germany. It is a silvery-white close-grained iron, very hard and rather
brittle, somewhat like cast iron but with silicon as the main additional
ingredient in place of carbon. It is difficult to cut or drill but may
be ground into shape by the new abrasives. It is rustproof and is not
attacked by sulfuric, nitric or acetic acid, hot or cold, diluted or
concentrated. It does not resist so well hydrochloric acid or sulfur
dioxide or alkalies.
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