Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
The apparatus which effects this transformation is essentially a
gigantic arc light in a chimney through which a current of hot air is
blown. The more thoroughly the air comes under the action of the
electric arc the more molecules of nitrogen and oxygen will be broken up
and rearranged, but on the other hand if the mixture of gases remains in
the path of the discharge the NO molecules are also broken up and go
back into their original form of NN and OO. So the object is to spread
out the electric arc as widely as possible and then run the air through
it rapidly. In the Schoenherr process the electric arc is a spiral flame
twenty-three feet long through which the air streams with a vortex
motion. In the Birkeland-Eyde furnace there is a series of semi-circular
arcs spread out by the repellent force of a powerful electric magnet in
a flaming disc seven feet in diameter with a temperature of 6300 deg. F. In
the Pauling furnace the electrodes between which the current strikes
are two cast iron tubes curving upward and outward like the horns of a
Texas steer and cooled by a stream of water passing through them. These
electric furnaces produce two or three ounces of nitric acid for each
kilowatt-hour of current consumed. Whether they can compete with the
natural nitrates and the products of other processes depends upon how
cheaply they can get their electricity. Before the war there were
several large installations in Norway and elsewhere where abundant water
power was available and now the Norwegians are using half a million
horse power continuously in the fixation of nitrogen and the rest of the
world as much again. The Germans had invested largely in these foreign
oxidation plants, but shortly before the war they had sold out and
turned their attention to other processes not requiring so much
electrical energy, for their country is poorly provided with water
power. The Haber process, that they made most of, is based upon as
simple a reaction as that we have been considering, for it consists in
uniting two elemental gases to make a compound, but the elements in this
case are not nitrogen and oxygen, but nitrogen and hydrogen. This gives
ammonia instead of nitric acid, but ammonia is useful for its own
purposes and it can be converted into nitric acid if this is desired.
The reaction is:
NN + HH + HH + HH --> NHHH + NHHH
Nitrogen hydrogen ammonia
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