Creative Chemistry: Descriptive of Recent Achievements in the Chemical IndustriesSlosson, Edwin E. (Edwin Emery)
Science
Creative Chemistry: Descriptive of Recent Achievements in the Chemical Industries
Slosson, Edwin E. (Edwin Emery)
Chemistry, Technical
Germany had a natural monopoly of potash as Chile had a natural monopoly
of nitrates. The agriculture of Europe and America has been virtually
dependent upon these two sources of plant foods. Now when the world was
cleft in twain by the shock of August, 1914, the Allied Powers had the
nitrates and the Central Powers had the potash. If Germany had not had
up her sleeve a new process for making nitrates she could not long have
carried on a war and doubtless would not have ventured upon it. But the
outside world had no such substitute for the German potash salts and
has not yet discovered one. Consequently the price of potash in the
United States jumped from $40 to $400 and the cost of food went up with
it. Even under the stimulus of prices ten times the normal and with
chemists searching furnace crannies and bad lands the United States was
able to scrape up less than 10,000 tons of potash in 1916, and this was
barely enough to satisfy our needs for two weeks!
[Illustration: What happened to potash when the war broke out. This
diagram from the _Journal of Industrial and Engineering Chemistry_ of
July, 1917, shows how the supply of potassium muriate from Germany was
shut off in 1914 and how its price rose.]
Yet potash compounds are as cheap as dirt. Pick up a handful of gravel
and you will be able to find much of it feldspar or other mineral
containing some ten per cent. of potash. Unfortunately it is in
combination with silica, which is harder to break up than a trust.
But "constant washing wears away stones" and the potash that the
metallurgist finds too hard to extract in his hottest furnace is washed
out in the course of time through the dropping of the gentle rain from
heaven. "All rivers run to the sea" and so the sea gets salt, all sorts
of salts, principally sodium chloride (our table salt) and next
magnesium, calcium and potassium chlorides or sulfates in this order of
abundance. But if we evaporate sea-water down to dryness all these are
left in a mix together and it is hard to sort them out. Only patient
Nature has time for it and she only did on a large scale in one place,
that is at Stassfurt, Germany. It seems that in the days when
northwestern Prussia was undetermined whether it should be sea or land
it was flooded annually by sea-water. As this slowly evaporated the
dissolved salts crystallized out at the critical points, leaving beds of
various combinations. Each year there would be deposited three to five
inches of salts with a thin layer of calcium sulfate or gypsum on top.
Counting these annual layers, like the rings on a stump, we find that
the Stassfurt beds were ten thousand years in the making. They were
first worked for their salt, common salt, alone, but in 1837 the
Prussian Government began prospecting for new and deeper deposits and
found, not the clean rock salt that they wanted, but bittern, largely
magnesium sulfate or Epsom salt, which is not at all nice for table use.
Public-domain text, read in full here on John Shaqi.
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