As quartz possesses the symmetry of the trigonal system and is thus
optically uniaxial, its optical properties are expressed, in common with
those of all trigonal, tetragonal, and hexagonal crystals, by an
ellipsoid of revolution, an ellipsoid the section of which perpendicular
to the principal axis—that of revolution, the maximum or minimum
diameter of the ellipsoid—is a circle. The optical properties are
consequently the same in all directions round this axis, which has
already been referred to by its common appellation of the “optic axis.”
The optic axis is identical in direction with the trigonal axis of
symmetry in the case of quartz or other trigonal crystal, and in the
cases of hexagonal and tetragonal crystals with the axes of hexagonal
and tetragonal symmetry, these three axes of specific symmetry being the
distinctive property of these three respective systems, which are thus
known in common as optically “uniaxial.”
Consequently, no double refraction is suffered by a ray transmitted
parallel to the optic axis, and the refractive index is equal in all
directions perpendicular to the optic axis, that is, for all rays
vibrating perpendicularly to the axis; hence the value of the refractive
index obtained along any such direction is one extreme value for the
whole crystal, and as already mentioned is distinguished by the letter
ω. The refractive index along the direction of the axis itself is the
other extreme value, and is labelled ε. It must be clearly appreciated,
however, that it is not the direction of transmission but that of
vibration perpendicular thereto, that is meant when it is said that, for
instance, the direction of the axis corresponds to the index ε. That is
to say, a ray the _vibrations_ of which occur parallel to the optic axis
of a uniaxial crystal is refracted to an amount which corresponds to the
refractive index ε, while a ray the vibrations of which occur
perpendicularly to the axis affords ω. The difference between ε and ω is
the measure of the double refraction of the crystal.
Public-domain text, read in full here on John Shaqi.
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