The fact that a perfect cleavage is exhibited by calcite had already
been observed by Erasmus Bartolinus in 1670, and in his “Experimenta
Crystalli Islandici” he gives a most interesting account of the great
discovery of immense clear crystals of calcite which had just been made
at Eskifjördhr in Iceland, minutely describing both their cleavage and
their strong double refraction. Huyghens in 1690 followed this up by
investigating some of these crystals of calcite still more closely, and
elaborated his laws of double refraction as the result of his studies.
There now followed a century which was scarcely productive of any
further advance at all in our real knowledge of crystals. It is true
that Boyle in 1691 showed that the rapidity with which a solution cools
influences the habit of the crystals which are deposited from it. But
neither Boyle, with all his well-known ability, so strikingly displayed
in his work on the connection between the volume of a gas and the
pressure to which it is subjected, nor his lesser contemporaries Lemery
and Homberg, who produced and studied the crystals of several series of
salts of the same base with different acids, appreciated the truth of
the great fact discovered by Guglielmini, that the same substance always
possesses the same crystalline form the angles of which are constant.
Even with the growth of chemistry in the eighteenth century, the opinion
remained quite general that the crystals of the same substance differ in
the magnitude of their angles as well as in the size of their faces.
We begin to perceive signs of progress again in the year 1767, when
Westfeld made the interesting suggestion that calcite is built up of
rhombohedral particles, the miniature faces of which correspond to the
cleavage directions. This was followed in 1780 by a treatise “De formis
crystallorum” by Bergmann and Gahn of Upsala, in which Guglielmini’s law
of the constancy of the cleavage directions was reasserted as a general
one, and intimately connected with the crystal structure. It was in this
year 1780 that the contact goniometer was invented by Carangeot,
assistant to Romé de l’Isle in Paris, and it at once placed at the
disposal of his master a weapon of research far superior to any
possessed by previous observers.
[Illustration:
FIG. 11.—Contact Goniometer as used by Romé de l’Isle.
]
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