bright colour, as the thickness increases adequately for the double
refraction retardation to reach the more brilliant second order
spectrum, a concluding effect which evokes the emphatic delight of even
the most phlegmatic philosopher, inured to scenes of beauty in natural
phenomena.
The series of experiments with quartz described in this and the previous
chapter, culminating with those revealing the alternate repetition of
extremely fine layers of right and left-handed quartz in amethyst, will,
it is hoped, have illustrated and rendered intelligible the important
structural principle of enantiomorphism or mirror-image symmetry. We
have only to imagine the layers to become thinner and thinner until we
approach ultimately the neighbourhood of the minute dimensions of the
chemical molecule, without as yet penetrating within the range of the
molecular forces; the two such oppositely constructed and intimately
blended structures, built up by atoms arranged oppositely screw-wise,
clockwise and anti-clockwise, will now form an ultramicroscopic mixture
of the two varieties in equal quantities, that is, in equal molecular
proportions.
Such a structure will exhibit the symmetry of the system to which the
two individuals belong, but instead of only displaying that of the
enantiomorphous class of that system, possessing lower than the full
symmetry, as each variety does when crystallised alone, it will now
display the full holohedral symmetry of the system. That is, the
symmetry is enhanced by this intimate blending of the two complementary
enantiomorphous forms, the two together supplying all the possible
elements of symmetry of which the system is capable. Moreover, as we
have seen in the case of the lamellar portion of the amethyst crystals
represented in Figs. 95 and 96, there will now be no sign of optical
activity, for the two opposite rotations are equal and destroy each
other.
Hence, such a compound crystal shows the holohedral symmetry of the
system, and is optically inactive. In such cases we are, in fact,
confronted with the phenomenon of pseudo-racemism, as defined in Chapter
XI. For we know that the two varieties are still present intact,
polarised light revealing them in the case of their grosser development
such as is found in amethyst, and the system of symmetry being clearly
the same, the forms developed being merely the sum of those of the two
individual varieties.
Amethyst thus affords us a gross demonstration of the nature of
pseudo-racemism, and as such has proved an exceedingly illuminating
study.
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