We can carry the process further, however, in imagination, until the two
differently helical molecules are themselves juxtaposed face to face,
right molecule to left molecule. When, however, this occurs, we have
entered into that most fascinatingly interesting region, the range of
molecular forces, a mysterious sphere of activities of which we are only
just beginning to learn something. Within this region of larger activity
the two oppositely constructed molecules are often known to combine
chemically to produce a molecular compound, just as potassium sulphate
molecules, for instance, will combine with those of magnesium sulphate
to form the well-known double salt. The double molecule now furnishes
the representative point of the space-lattice, in other words, a new
space-lattice is now erected, the units of which may be taken to be the
representative points of the double molecules. Such a space-lattice will
of necessity be of a totally different character to the old one
corresponding to the single molecule of either variety (for each variety
has the same space-lattice, the points, however, representing
differently, enantiomorphously, orientated atomic details). That is to
say, we shall have an entirely new kind of crystal produced, in all
probability belonging to a different crystal system. It is known as a
racemic compound, as described in Chapter XI.
This is exactly what happens in the case of tartaric acid, the two
varieties, dextro or right-handed tartaric acid and lævo or left-handed
tartaric acid, not forming pseudo-racemic crystals of like but enhanced
(holohedral) symmetry, but a truly molecular compound, the well-known
inactive racemic acid, in which the phenomenon of “racemism” was first
discovered and from which it took its name.
Public-domain text, read in full here on John Shaqi.
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