One of the most deeply interesting aspects of a crystal, especially from
the point of view of the history of crystallographic investigation,
concerns the mysterious process of its growth from a solution (in a
solvent) of the substance composing it. The story of the elucidation, as
far as it has yet been accomplished, of the nature of crystallisation
from solution in water is one of the most romantic which the whole of
scientific progress can furnish. Again we are struck with the
parallelism between crystals and living objects. For just as the
discovery of bacteria, the infinitesimal germs of life, has given an
immense impetus to our knowledge of disease and been blessed with most
beneficent effects in combatting the ravages of the latter, so the
discovery that crystal-germs of most common crystallised substances, of
no larger size than bacteria, are floating about in our atmosphere, and
ready at any time to drop into our solutions and, if the latter are in
the proper receptive condition, to set them crystallising, is little
less marvellous, and has had as profound an effect on our knowledge of
the process of crystallisation. A true story, told to the Royal Society
the other day, may serve to illustrate the point. A new chemical
compound had been discovered, and at the time there could obviously be
no crystal-germs, minute crystallites of the dimensions of possibly only
a comparatively few chemical molecules, of this hitherto unknown
substance floating about in the air. It was found impossible to obtain
the deposition of crystals in the ordinary way, from solutions of the
substance in its ordinary solvent, although they were in the condition
of proper receptivity above referred to, on account of the absence of
such germs in the air. But later on, when the air of the laboratory had
become impregnated with such germs, on account of the daily handling of
the substance in the laboratory, no difficulty was any longer found in
obtaining good crystals quite readily from these solutions.
We are at first inclined to wonder whether such extraordinary statements
can possibly be sober facts. Yet such is, indeed, the case, and it will
be very well worth devoting a chapter to the story of how we have at
length arrived at definite knowledge concerning the process of
crystallisation from the state of solution in water. For water is the
ordinary solvent from which we obtain our crystals, that is, such as are
prepared artificially in the laboratory. The laws which have been
discovered to hold for aqueous solutions are, however, equally
applicable to the cases where other solvents are used, such for instance
as the usual organic solvents like alcohol, ether, chloroform, and
benzene.
Public-domain text, read in full here on John Shaqi.
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