Now a molecular compound is notoriously regarded by chemists as a type
of chemical compound of low stability, molecular attraction or affinity
not being nearly so powerful as atomic affinity. Hence, under suitable
conditions it may be possible to induce the two component varieties to
crystallise out separately from the solution of the racemic compound. In
the case of racemic acid itself this does not readily happen, but in the
cases of certain of its metallic salts, sodium ammonium racemate, for
instance, specific conditions are known under which the two varieties of
crystals, right and left-handed respectively, may be separately
crystallised out from the solution, some of which conditions were
referred to in Chapter XI. Racemic acid itself, however, crystallises
quite differently to the two tartaric acids, namely, in triclinic
prismatic crystals. These are, in fact, absolutely different from the
monoclinic crystals of the dextro and lævo varieties of ordinary
tartaric acid, for racemic acid takes up also a molecule of water of
crystallisation on separating from its aqueous solution. There are
certain chemical differences also, due to the chemical union of the two
enantiomorphous molecules into a single double molecule, such, for
instance, as greater facility of reduction by hydriodic acid to succinic
acid.
Thus our experiments with quartz have afforded us the means of acquiring
a clear idea of the nature of this most interesting type of crystal
structure which involves the principle of mirror-image symmetry. Racemic
acid and its similar structures, racemic compounds in general, are known
as “externally compensated” structures, the reflective principle here
acting externally to the single enantiomorphous molecule. It is but
another step, however, to imagine internal compensation of
enantiomorphous parts of a molecule, by mirror-image combination of such
parts, such as in all probability occurs in the case of the truly
inactive fourth variety of tartaric acid, in order to comprehend how the
principle enabled the 165 types of homogeneous structure involving this
kind of repetition to be arrived at, and thus, together with the 65
regular point-systems already known, to afford us the complete set of
230 types of homogeneous structures possible to crystals.
CHAPTER XV
HOW A CRYSTAL GROWS FROM A SOLUTION.
Public-domain text, read in full here on John Shaqi.
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