A beautiful experimental demonstration of crystallisation from the
metastable and labile conditions of solution respectively is afforded by
potassium bichromate, K_{2}Cr_{2}O_{7}. When deposited slowly from a
metastable solution under conditions of quietude, this salt is slowly
deposited in bright orange coloured and excellently formed crystals,
often of considerable size, belonging to the triclinic system of
symmetry; they are bounded by good pinakoidal (pairs of parallel) faces
intersecting in sharp edges. But when the crystallisation occurs from a
labile solution, being much more rapid, it takes the form of feathery or
arborescent branching skeletal growths, there being inadequate time for
the formation of well-developed crystals.
Fig. 99, Plate XXI., is a photographic reproduction of well-formed
crystals of potassium bichromate, grown from a solution in the
metastable condition on a microscope slip, just as they are seen through
the microscope in the slow act of formation, employing a 1½ inch
objective. The crystallisation had been started by germ crystals of the
salt falling in from the air, after which the drop, placed within the
ring of hardened gold size on the slide, had been covered with a
cover-glass, under which the crystallisation had proceeded with
sufficient slowness to enable a successful photograph to be taken, when
the camera was subsequently attached above the vertically arranged
microscope. An upright micrographic apparatus had been designed by the
author specially for this photography of growing crystals, many of the
results of which are reproduced in this book.
[Illustration:
_PLATE XXI._
FIG. 99.—Potassium Bichromate slowly crystallising from a Metastable
Solution.
]
[Illustration:
FIG. 100.—Potassium Bichromate rapidly crystallised from a Labile
Solution.
CHARACTERISTIC DIFFERENCE IN THE CRYSTALS DEPOSITED FROM METASTABLE
AND LABILE SOLUTIONS.
]
Fig. 100 is the reproduction of another photograph taken under similar
conditions, but employing a hot and somewhat more concentrated solution
of potassium bichromate, and making the exposure at the moment when, in
the particular field chosen, a rapid labile crystallisation was just
completing itself, the rapidity of growth of the feathery skeletal
crystals having just become arrested. Indeed, the branches are
frequently terminated by small well-formed crystals, the rapid growth
having been succeeded by a final slow crystallisation where the solution
had discharged its labile excess and attained once more the metastable
condition.
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