We have seen in the foregoing pages that a crystal is usually a solid,
highly organised in a homogeneous manner, and, unless the symmetry be
developed to its highest extent, the crystal then belonging to the cubic
system, it is also in general anisotropic, that is, it exhibits double
refraction. Section-plates of it, more or less thin according to the
strength of the double refraction, exhibit colours in parallel polarised
light, and show the phenomenon of a single optic axis, or of two optic
axes, in convergent polarised light. Every variety of hardness, however,
is displayed, from that of the diamond down to that of a crystal as soft
as gypsum, and even softer. Moreover, many of the softer crystallised
substances develop the property of permitting one layer to glide over
another by gentle side pressure with a knife blade, when inserted in an
edge or face in an attempt to cut the crystal. Calcite and ice, for
instance, both possess such planes of gliding of the structural units
over one another in layers. There are also the border line cases of
crystals so soft as to be readily bent, and many well-known viscous
substances crystallisable only with great difficulty, some of which form
pliable crystals.
But in the year 1876 Lehmann discovered a new property in an already
remarkable substance, iodide of silver, AgI, namely, that at
temperatures superior to 146° C. it can flow like a viscous liquid,
while exhibiting several of the properties which are characteristic of
crystals. Silver iodide is dimorphous, exhibiting a hexagonal form at
the ordinary temperature, which persists up to 146°. But during the
heating to the latter temperature a regularly accelerating diminution of
volume occurs, the feeble expansion in directions perpendicular to the
axis being overbalanced by a considerable contraction along the axis,
both quantities having been accurately measured so long ago as the year
1867 by Fizeau, by means of his delicate interference dilatometer. This
contraction, so unusual an occurrence with increase of temperature,
culminates at 146°, according to Mallard and Le Chatelier, in a sudden
change of condition into a cubic modification, accompanied by absorption
of heat. Now Lehmann, studying this cubic modification of silver iodide
under a microscope which he had devised—specially adapted for
observations at temperatures higher than the ordinary, by being supplied
with the means of heating the object under observation—found that it was
not only plastic, but actually a liquid.
[Illustration:
FIG. 102.—Lehmann’s Crystallisation Microscope.
]
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