This highly interesting explanation of Miers, supported as it is by the
work of Wulff, and confirmed also in many respects by the observations
of the author, whose great aim throughout his investigations has been to
avoid the production of such vicinal faces, throws an important light on
the nature of the act of crystallisation. It renders the reason clear
why crystals which are very slowly grown from solutions only feebly
supersaturated and under conditions of absolute rest, protected from
either air currents or preventable earth tremors—conditions which the
author has taken quite exceptional pains to procure for the preparation
of the crystals used in the investigation of the sulphates and selenates
of the rhombic simple salt series and monoclinic double salt series—are
occasionally obtained quite free from any sign of such vicinal faces.
They are small perfect individuals exhibiting primarily the faces of
high reticular density, that is, the faces of the simple forms of low
rational indices; and these faces are absolutely plane, affording one
single brilliant image of the goniometer signal, which can be adjusted
with great precision to the cross-wires of the telescope. For the slower
the growth, the more time is afforded for the escape of the water
molecules, and for the salt molecules to deposit themselves as directed
by the molecular guiding force of crystallisation, along the planes of
high reticular density. In many of his experiments Miers expressly
stirred the solution, to prevent concentration currents, which had been
considered by Wulff of importance in the process, from coming into play
and causing unknown effects. Hence his experiments in which vicinal
faces were produced are not comparable with the author’s slow growths.
The work of Miers assists in the proof that the constancy of angle to
within one or two minutes of arc is a real property of the crystals of a
substance. For previously the frequent presence of vicinal faces rather
than the simple forms of high reticular density, and which had been
mistaken for the latter, had caused Pfaff in 1878[25] and others to
conclude that variations from the true crystal angle amounting to as
much as 30′ were of common occurrence as the result of strain during
deposition.
Brauns[26] in 1887 made a careful series of measurements of very good
octahedral crystals of lead nitrate, and found 13′ 20″ the largest
deviation of a good image from the theoretical position. He imputed it
to the action of gravity as a disturbing cause during deposition. The
researches of Miers have cleared away all this misconception, in proving
that the bright images referred to, taken for those of the simple
primary form, are not such at all, but vicinal faces of very low
reticular density.
CHAPTER XVI
LIQUID CRYSTALS.
Public-domain text, read in full here on John Shaqi.
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