Lehmann would appear to have made one point very clear, which at once
removes an objection long felt by the author to the theory of crystal
structure as it stands at present, namely, that the chemical molecule is
endowed with a directive orientative force, which is certainly concerned
in crystallisation. To assume, as has been done, just because it is not
necessary from the point of view of the geometrician in developing his
possible homogeneous structures, that no directive force is operative in
crystallisation, and that all is a mere question of the most convenient
mechanical packing of the molecules, is, in the author’s opinion, going
beyond what the experimental facts justify. If Lehmann’s discovery of
flowing crystals does nothing more than return to the molecule the
property always hitherto attributed to it, of possessing in itself some
directive force by reason of which it arranges itself homogeneously by
mutual accommodation with its similarly endowed fellow molecules, when
its motion in the liquid state has been sufficiently arrested by its
approach to its fellows within the range of molecular action (four or
five molecular diameters), either by cooling or the falling out of
previously separating solvent molecules, it will have achieved a notable
thing.
What does occur at the moment of crystallisation is at the present time
one of the most interesting unsolved questions in crystallography, and
one calling most urgently for solution. Attention was directed to the
problem in the last chapter, in connection with the suggestive work of
Miers on vicinal faces. It was shown that it was only when the directive
force had time to come properly into operation that the primary faces of
fundamental importance were produced, and that when the crystallisation
was rapid vicinal faces formed instead. Lehmann believes that a single
kind of chemical molecule is only capable of producing a single specific
space-lattice, and that polymorphism is due to alteration of the
molecules themselves at the critical temperature of transformation. He
showed so far back as 1872 that this limit could be actually observed
under the microscope, as a definite line of demarcation between the two
varieties as the temperature fell, one side of the field attaining the
critical temperature slightly before the other, and the defining line
between the two kinds thus travelling over the field. Internal friction
did not appear to Lehmann to enter into the question at all, as he
considered it would have done if a rearrangement of the molecules were
the sole cause of the change. The molecules themselves, he states, must
have been undergoing change, and such rearrangement of them as occurred
must have been due to that fact.
[Illustration:
_PLATE XXIV._
FIG. 117.—Arrangement of Astatic Magnet-systems in a Plane.
]
[Illustration:
FIG. 118.—Arrangement of Astatic Magnet-systems in Space.
]
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