These theoretical ideas of Lehmann have naturally called forth much
discussion, criticism, and scepticism. But, so far, his experimental
facts have been fully substantiated by further investigation. Much more
practical work is urgently required, however, before the subject can be
considered as laid on a secure foundation. So much may be said, however,
that it is clear that we must concede the existence of a directive force
of crystallisation, and not be led by the pure geometry of the subject
of crystal structure to ignore facts of such interest and undoubted
importance as have been brought into prominence by the remarkable work
of Lehmann.
A further interesting contribution has recently been made by
Vorländer[27] to the facts regarding the relationship between chemical
constitution and the formation of liquid crystals. It must have already
struck the reader that most of the substances which exhibit liquid
crystals are composed of a large number of chemical atoms, being either
long-chain compounds of the fatty acids or complex derivatives of the
hydrocarbon benzene, C_{6}H_{6}; also that many of the latter are “para”
compounds, that is, derivatives in which the substitution groups are
inserted in the benzene ring of six carbon atoms in the “para” position,
which is that at the opposite corner of the hexagon to the carbon atom
to which a substitution group has already been attached. This renders
the para compounds the most extended in a straight line of all the
benzene derivatives. Now Vorländer finds that a particularly favourable
condition for the production of liquid crystals is a linear structure of
the molecule. As the para substitution products of benzene derivatives
possess this elongated structure, many of them exhibit the development
of liquid crystals. The more linearly extended the structure becomes,
that is, the longer the straight chain of atoms is, the more favourable
become the conditions. The advent of a third substitution group,
however, which would have the effect of producing a kink in the chain,
or of bending it, appears to destroy the possibility of the production
of liquid crystals. This interesting observation may afford the key to
many of the extraordinary phenomena of liquid crystals which have been
described, and is undoubtedly one of prime importance. Further
favourable conditions for the formation of liquid crystals, according to
Vorländer,[28] are the aromatic character, and the presence of the
doubly-linked carbon and nitrogen groups C:C, C:N, and N:N, which are
usually so rich in energy.
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