The idea of the formation of a specific crystalline homogeneous
structure, merely because the mechanical fitting-in of the molecules
occurs with the minimum of trouble or maximum of ease for this
particular type of all the 230 possible types, is certainly not
applicable to the case of Lehmann’s liquid crystals. With this,
moreover, is also connected the question of softness or hardness of
crystals, which was referred to at the opening of this chapter. For the
so-called liquid crystals are extreme cases of softness, and yet in
these cases the molecules must still be arranged in accordance with the
internal structure of a crystal, either parallel or enantiomorphously
definitely orientated with respect to each other, for otherwise it is
not possible to account for the optical properties resembling the
orientated ones of a crystal. Yet the condition being that of a liquid,
the molecules must be able readily to pass and roll over each other, and
hence cannot be at the close quarters where mere “fitting-in” comes into
play.
Again, as has been pointed out earlier, many soft crystals, even such as
calcite, which are only relatively soft, attaining the position of as
much as four in the scale of hardness, readily exhibit the property of
being deformable upon glide-planes. The molecules in these cases have
been shown to undergo a movement which has two components, a
transference and a rotation, a fact which has been thoroughly
substantiated by optical investigations of the parts of the crystal
concerned before and after gliding. There cannot, therefore, have been
merely “fitting-in” of the molecules, but their orientated positions
must have been determined and maintained by the organising force, which
is probably purely physical and not chemical, but is nevertheless the
cause of crystallisation; it draws the molecules within a certain range
of each other, corresponding to and dependent upon the temperature,
causes or enables them to arrange themselves in the marshalled order of
the particular type among the 230 possible arrangements, and keeps them
at the same time from approaching nearer to each other than within these
prescribed limits corresponding to the temperature. It is doubtless
within these limits that gliding can occur parallel to such planes as
leave the molecules most room for the purpose, and which are directions
of least resistance.
[Illustration:
FIG. 119.—Lehmann’s Crystallisation Microscope arranged for
Projection.
]
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