indeed, so obvious that any further development of the theory must of
necessity take account of it.
A precise statement of their conception has recently been made by Prof.
Pope in an excellent Report on the Progress of Crystallography, issued
by the Chemical Society early in the year 1909. He states that they
(Pope and Barlow) “regard the whole of the volume occupied by a
crystalline structure as partitioned out into polyhedra, which lie
packed together in such a manner as to fill the whole of that volume
without interstices. The polyhedra can be so selected that each
represents the habitat of one component atom of the material, and are
termed the spheres of atomic influence of the constituent atoms. Up to
this point no assumption is made other than that clearly indicated by
the result of crystallographic measurements, namely, that each atom
present in a crystalline structure exerts a distinct morphological
effect—or, what is the same thing, appropriates a certain definite
volume. The assumption is next made that the crystalline structure,
which is resolvable into individual molecules and ultimately into
individual atoms, exists as such by reason of equilibrium set up between
opposing attractive and repulsive forces operating between the component
atoms, and that this equilibrium results in the polyhedra representing
the spheres of atomic influence assuming shapes which are as nearly as
possible spherical.... The polyhedra thus arrived at may be regarded as
derived by compression of a close-packed assemblage of deformable,
incompressible elastic spheres,[29] the compression sufficing for the
practical extinction of the interstitial space. When such an assemblage
is released from pressure it is evident that in place of polyhedra, the
shapes of which approximate as closely as possible to the spherical,
closely packed spheres are presented; the distances between the sphere
centres can be substantially in the same ratios as the distances between
the centres of the corresponding polyhedra in the unexpanded mass, and
the equilibrium condition of maximum sphericity of the polyhedra will be
presented in the expanded mass of spheres by the existence of the
maximum number of contacts between spheres. The whole method of treating
the primary assumption thus resolves itself into finding close-packed
assemblages of spheres of various sizes representing by their relative
volumes the spheres of influence of the component atoms of any
particular crystalline structure.”
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