Moreover, there is yet another view, that of Sollas,[30] that the
packing of the molecules is a more open one altogether, a view to which
he has been guided by consideration of the molecular volume. Sollas has
offered some remarkable explanations of crystal structure, notably in
the case of the dimorphous forms of silver iodide. The abnormal
contraction which occurs on heating this interesting substance, and its
sudden transformation at 146° from the ordinary hexagonal into a cubic
modification as discovered by Lehmann, appear capable of very clear
explanation on the basis of his theory. According to this theory of
Sollas the volumes of the spheres of influence of the atoms of the
different elements of the same family group, such as those of the group
of alkali metals or those of the halogens, chlorine, bromine, and
iodine, vary progressively in a manner which is dependent on the atomic
volumes of the elements, which have a real comparative significance when
the elements belong to the same family group.
It is probable that there is a considerable substratum of truth behind
these various apparently conflicting views, and what is now required is
that the germ of real fact shall be winnowed from the husk of fallacious
speculation, just as occurred in the happy recent settlement of the old
issue between Haüy and Mitscherlich. As in that case, moreover, it will
be experimental work of superlative accuracy which can alone offer the
desirable evidence on which a satisfactory arbitration can be founded.
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