crystallisation, as does also white vitriol, zinc sulphate; but blue
vitriol, copper sulphate, crystallises with only five molecules of water
under ordinary atmospheric conditions of temperature and pressure.
Moreover, copper sulphate forms crystals which belong to the triclinic
system, while the sulphates of zinc and iron are dimorphous, the common
form of zinc sulphate, ZnSO_{4}.7H_{2}O, being rhombic, like Epsom
salts, the sulphate of magnesia which also crystallises with seven
molecules of water, MgSO_{4}.7H_{2}O, while that of ferrous sulphate,
FeSO_{4}.7H_{2}O, is monoclinic, facts which still further complicate
the crystallography of this group and which were quite unknown to
Beudant and were unobserved by him. But Beudant showed that the addition
of fifteen per cent. of ferrous sulphate to zinc sulphate, or nine per
cent. to copper sulphate, caused either zinc or copper sulphate to
crystallise in the same monoclinic form as ferrous sulphate. He also
showed that all three vitriols will crystallise in mixed crystals with
magnesium or nickel sulphates, the ordinary form of the latter salt,
NiSO_{4}.7H_{2}O, being rhombic like that of Epsom salts.
The idea that two chemically distinct substances not crystallising in
the cubic system, where the high symmetry determines identity of form,
can occur in crystals of the same form, was most determinedly combated
by Haüy, and the lack of chemical analyses in Beudant’s work, and the
altogether incorrect “vicarious” explanation given by von Fuchs, gave
Haüy very grave cause for suspicion of the new ideas. The previous
observations of Rome de l’Isle in 1772, Le Blanc in 1784, Vauquelin in
1797, and of Gay-Lussac in 1816, that the various alums, potash alum,
ammonia alum, and iron alum, will grow together in mixed crystals or in
overgrowths of one crystal on another, when a crystal of any one of them
is hung up in the solution of any other, does not affect the question,
as the alums crystallise in the cubic system, the angles of the highly
symmetric forms of which are absolutely identical by virtue of the
symmetry itself.
Public-domain text, read in full here on John Shaqi.
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