under the ordinary circumstances of temperature and pressure three of
the salts form most readily the rhombic crystals, while the other two
take up most easily the monoclinic form. Mitscherlich then mixed the
solutions of the different salts, and found that the mixed crystals
obtained presented the form of some one of the salts employed. Thus even
so early in his work Mitscherlich indicated the possibility of
dimorphism. Moreover, before the close of the year 1819 he had satisfied
himself that aragonite is a second distinct form of carbonate of lime,
crystallising in the rhombic system and quite different from the
ordinary rhombohedral form calcite. Hence this was another undoubted
case of dimorphism.
During this same investigation in 1819, Mitscherlich studied the effect
produced by mixing the solution of each one of the above-mentioned seven
sulphates of dyad-acting metals with the solution of sulphate of potash,
and made the very important discovery that a double salt of definite
composition was produced, containing one equivalent of potassium
sulphate, one equivalent of the dyad sulphate (that of magnesium, zinc,
iron, manganese, nickel, cobalt, or copper), and six equivalents of
water of crystallisation, and that they all crystallised well in similar
forms belonging to the monoclinic system. Some typical crystals of one
of these salts, ammonium magnesium sulphate, are illustrated in Fig. 30
(Plate VII., facing page 44). This is probably the most important series
of double salts known to us, and is the series which has formed the
subject of prolonged investigation on the part of the author, no less
than thirty-four different members of the series having been studied
crystallographically and physically since the year 1893, and many other
members still remain to be studied. An account of this work is given in
a Monograph published in the year 1910 by Messrs Macmillan & Co., and
entitled, “Crystalline Structure and Chemical Constitution.”
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account