Here was a perfectly clear case of an element—not liable to any charge
of difference of chemical composition such as might have applied to the
cases of sodium dihydrogen phosphate, carbonate of lime, and iron
vitriol and its analogues, which he had previously described as cases of
the same substance crystallising in two different forms—which could be
made to crystallise in two different systems of symmetry at will, by
merely changing the circumstances under which the crystallisation
occurred. His explanation being thus proved absolutely, he no longer
hesitated, but at once applied the term “dimorphous” to these substances
exhibiting two different forms, and referred to the phenomenon itself as
“dimorphism.” The case of carbonate of lime had given rise to prolonged
discussion, for the second variety, the rhombic aragonite, had been
erroneously explained by Stromeyer, after Mitscherlich’s first
announcement in 1819, as being due to its containing strontia as well as
lime, and the controversy raged until Buchholz discovered a specimen of
aragonite which was absolutely pure calcium carbonate, so that
Mitscherlich’s dimorphous explanation was fully substantiated.
Dimorphism is very beautifully illustrated by the case of the trioxide
of antimony, Sb_{2}O_{3}, a slide of which, obtained by sublimation of
the oxide from a heated tube on to the cool surface of a glass
microscope slip, is seen reproduced in Fig. 50, Plate XI. The two forms
are respectively rhombic and cubic. The rhombic variety usually takes
the form of long needle-shaped crystals, which are shown in Fig. 50
radiating across the field and interlacing with one another; the cubic
variety crystallises in octahedra, of which several are shown in the
illustration, perched on the needles, one interesting individual being
poised on the end of one of the needles. The two forms occur also in
nature as the rhombic mineral valentinite and the cubic mineral
senarmontite, which latter crystallises in excellent regular octahedra.
Antimonious oxide, moreover, is not only isomorphous, but isodimorphous
with arsenious oxide, a slide of octahedra of which has already been
reproduced in Fig. 3, Plate I., in Chapter I. For besides this common
octahedral form of As_{2}O_{3} artificial crystals of arsenious oxide
have been prepared of rhombic symmetry, resembling valentinite. Hence
the two lower oxides of arsenic and antimony afford us a striking case
of the simultaneous display of Mitscherlich’s two principles of
isomorphism and dimorphism.
Thus the position in 1826 was that Mitscherlich had discovered the
principle of isomorphism, and had also shown the occurrence of
dimorphism in several well-proved specific cases, and that he regarded
at this time isomorphism as being a literal reality, absolute identity
of form.
[Illustration:
_PLATE XI._
FIG. 50.—Rhombic Needles and Cubic Octahedra of Antimony Trioxide
obtained by Sublimation. An interesting Example of Dimorphism.
]
[Illustration:
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