The experiment as thus performed is one of the most beautiful
imaginable, and it can readily be understood how delighted were
Mitscherlich’s audience on the occasion of its first performance by him.
The author has since discovered no less than six other cases of
substances which exhibit crossed-axial-plane dispersion of the optic
axes, in the course of his investigations, one of which is illustrated
in Plate XIII., facing page 108; and, moreover, has arrived at a general
explanation of the whole phenomenon, the main points of which are that
such substances, besides showing very feeble double refraction (the two
extreme of the three refractive indices being very close together), also
exhibit very close approximation of the intermediate refractive index β
to either the minimum index α or the maximum index γ. Also, change of
temperature, or of wave-length, or most usually both, must so operate as
to bring the two indices closest together into actual identity and then
to pass beyond each other, these two indices thus exchanging positions,
the extreme one becoming the intermediate index. In other words, the
uniaxial cross and circular rings are produced owing to two of the three
refractive indices (corresponding to the directions of the three
rectangular axes of the ellipsoid which, in general, expresses the
optical properties of a crystal) becoming equal at the particular
temperature at which the phenomenon is observed to occur, and for light
of the specific wave-length in question. The ellipsoid of general form
which represents the optical properties of a biaxial crystal thus
becomes converted into a rotation ellipsoid corresponding to a uniaxial
crystal. Brookite and the triple tartrate are excellent examples of the
predominance of the effect of change of wave-length, for the optic axes
are separated in both cases widely in one plane for red light and almost
equally widely in the perpendicular plane for blue light. The new cases
observed by the author are sensitive both to change of wave-length and
to change of temperature, and so fall midway between the cases just
quoted and the case of gypsum. The cause of it, in four of these new
instances, is a very interesting one, connected with the regular change
of the refractive indices in accordance with the law of progression in
an isomorphous series according to the atomic weight of the alkali metal
present, which will be discussed in Chapter X.
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