This interesting and beautiful investigation of Miers thus gave us an
inkling of the truth, that small angular differences do exist between
the members of isomorphous compounds. It paved the way for, and indeed
partly suggested, the author’s systematic investigation of the
sulphates, selenates, and double salts of the alkali series of metals, a
brief account of the main results of which will be given in Chapter X.
CHAPTER IX
THE CRYSTAL SPACE-LATTICE AND ITS MOLECULAR UNIT CELL. THE 230
POINT-SYSTEMS OF HOMOGENEOUS CRYSTAL STRUCTURE.
The interval between the morphotropic work described in the last chapter
and the present time has been remarkable for the completion of the
geometrical and mathematical investigation, and the successful
identification, of all the possible types of homogeneous structures
possessing the essential attributes of crystals. It has now been
definitely established that there are 230 such types of homogeneous
structures possible, and the whole of them conform to the conditions of
symmetry of one or other of the thirty-two classes of crystals. This
fact is now thoroughly agreed upon by all the authorities who have made
the subject their special study, and may truly be considered as
fundamental.
There has long been a consensus of opinion that the crystal edifice is
built up of structural units which can be likened to the bricks or stone
blocks of the builder, but which in the case of the crystal are so small
as to be invisible even under the highest power of the microscope. The
conceptions of their nature, however, have been almost as numerous as
the investigators themselves, everyone who has thought over the subject
forming his own particular ideas concerning them. We have had the
“Molécules intégrantes” of Haüy, the “Polyhédres” of Bravais, the
“Fundamentalbereich” of Schönflies, the “Parallelohedra” of von Fedorow,
and the fourteen-walled cell, the “Tetrakaidecahedron” of Lord Kelvin,
and again the “Polyhedra” of Pope and Barlow. Ideas have thus been
extremely fertile, and indeed almost every variety of speculation has
been indulged in as to the shape and nature of the unit of the structure
which can exhibit such remarkable evidences of organisation and such
extraordinary optical and other physical properties as those of a
crystal.
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