There is one inherent difficulty, however, which renders all such
speculations more or less chimerical, until we know very much more as to
the structure of the chemical atom, and the organisation of the
corpuscles composing it. Such speculations, however, are deeply
interesting, and the difficulty alluded to accounts largely for the
great variety of conception possible. It is this, that the matter of the
molecules, and again that of the atoms composing them, is not
necessarily, nor even probably, continuous and in contact throughout,
but that on the contrary the space which may legitimately be assigned to
the unit of the structure is partly void. How much of this unit space is
matter and how much is unoccupied, and how the one is related to the
other as regards its position or distribution in space, we have yet no
means of knowing, although there are signs that the day is not far
distant when we shall know at least something concerning it. The recent
brilliant work of Sir J. J. Thomson and his school of physicists has
rendered it clear that the chemical atom is composed of cycles of
electronic corpuscles, the orbital motions of which determine its
boundaries.
In this condition of our knowledge obviously the only safe course is
to consider each atom of the chemical molecule as occupying a “sphere
of influence,” within the limits of which the material parts of the
atom, the corpuscles in organised motion, are confined. The
“Fundamentalbereich” of Schönflies and the “Sphere of Influence” of
Barlow, are the conceptions which in all probability have the greatest
value in the present state of our knowledge, and if we adopt the
latter we shall not be committing ourselves to anything more than the
experimental facts fully warrant.
It may be quite definitely stated, however, that there is a considerable
amount of experimental evidence that the unit of the space-lattice of
the crystal structure is certainly not more complex than the chemical
molecule, the idea of an aggregation of chemical molecules to form a
“physical molecule” acting as a structural unit having proved to be a
misleading myth.
Fortunately, however, there is no necessity whatever to introduce the
subject of the actual shape of the unit, and the greatest progress has
been effected by disregarding it altogether, and agreeing to the
representation of the unit by a point. This leads us at once to perceive
the importance of the brilliant work of the geometricians, who have now
completed their theory of the homogeneous partitioning of space into
point-systems possible to crystals, the structural units of the latter
being regarded as points. The investigations extend from those of
Frankenheim in the year 1830 to the finishing touches given by Barlow in
1894, and prominently standing forth as those of the greatest
contributors to the subject, besides the two investigators just
mentioned, are the names of Bravais, Sohncke, Schönflies and von
Fedorow.
Public-domain text, read in full here on John Shaqi.
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