Now the faces of the crystal parallel to each two of the three sets of
parallel lines forming the space-lattice will be the three pairs of
axial-plane faces, and any fourth face inclined to them must be got by
removing parallelepipedal blocks in step-wise fashion, precisely like
bricks, as already shown in Fig. 12 (page 28) in Chapter III., in order
to illustrate the step by step removal of Haüy’s unit blocks. It will
readily be seen that if one more cell be removed from each row than from
the row below it, the line of contact touching the projecting corner of
the last block of each row will be inclined more steeply than if two
more cells were removed from each row. Moreover, the angle varies
considerably between the two cases, and if three blocks are removed at a
time the angle gets very small indeed. Hence, there cannot be many such
planes possible, and we see at once why the indices of the faces
developed on a crystal are composed of low whole numbers and why the
forms are so relatively few in number. Owing to the minuteness of a
chemical molecule, all the irregularities of such a surface are
submicroscopic, and the general effect to the eye is that of a smooth
plane surface.
The space-lattice arrangement of the molecules in the crystal structure
thus causes the crystal to follow the law of rational indices, by
limiting and restricting the number of possible facial forms which can
be developed. It also determines which one of the seven systems of
symmetry or styles of crystal architecture the crystal shall adopt. It
does not determine the details of the architecture, however, that is, to
which of the thirty-two classes it shall conform, this not being the
function of the molecular arrangement but of the atomic arrangement that
is, of the arrangement of the cluster of atoms which form the molecule,
and this leads us to the next step in the unravelling of the internal
structure of crystals.
The credit of this next stage of further progress is due to Sohncke,
whose long labours resulted in the discrimination and description of
sixty-five “Regular Point-Systems,” homogeneous assemblages of points
symmetrically and identically arranged about axes of symmetry, which are
sometimes screw axes, that is, axes about which the points are spirally
distributed. Sohncke’s point-systems express the number of ways in which
symmetrical repetition can occur. Moreover, the points may always be
grouped in sets or clusters, the centres of gravity of which form a
Bravais space-lattice.
This latter fact is of great interest, for it means that Sohncke’s
points may represent the chemical atoms, and that the stereometric
arrangement of the atoms in the molecule is that which produces the
point-system and determines the crystal class, while the whole cluster
of atoms forming the molecule furnishes, as above stated, the
representative point of the space-lattice.
Public-domain text, read in full here on John Shaqi.
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