The second illustration is taken from the optical properties. Fig. 61
represents graphically the regular diminution of double refraction (the
difference between the two extreme indices of refraction α and γ) which
accompanies increase of the atomic weight of the metal present. The
diagram exhibits the closing up of the two spectra afforded by three
analogously orientated 60°-prisms, one of each of the three salts, such
as was used in determining two of the refractive indices of the salt.
Each prism produces two refracted rays from the single ray furnished by
the collimator of the spectrometer, and consequently two images of the
signal-slit of the collimator when monochromatic light is used, or two
spectra if white light be employed. The Websky signal-slit is narrow at
the centre to enable an accurate allocation to the vertical cross-wire
of the telescope to be made, but wide at its top and bottom ends, in
order to transmit ample light, and Fig. 61 shows four images of this
signal produced by each prism, namely, one R in red C-hydrogen light and
another B in greenish-blue F-hydrogen light belonging to each of the two
spectra, in order to locate the two ends of each of the latter, coloured
monochromatic light of each of the two colours in turn and of the exact
C and F wave-lengths having been fed to the spectrometer from the
spectroscopic illuminator. It will be observed in the case of the top
row that the two spectra, each indicated by the adjacent red and
greenish-blue images, are well apart, the relative distance being about
that actually observed in the case of potassium sulphate. They are
nearer together, however, in the second row, which indicates what is
observed in the case of the analogous rubidium salt, and in the lowest
row representing the relative distances of the two spectra apart in the
case of the cæsium salt, they are so close together as to overlap; for
in this latter case the greenish-blue image of the left-hand spectrum,
corresponding to the a index of refraction, occupies the same position
as the image for yellow sodium light of the right-hand spectrum
corresponding to γ would occupy in the case of cæsium sulphate, the a
refractive index for F-light being 1·5660 and the γ index for Na-light
being 1·5662. The progression of the alteration of the amount of the
double refraction is thus very striking, as the atomic weight of the
metal is varied.
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