The third illustration of the law of progression with atomic weight is
also an optical one, and is taken from the monoclinic series of double
sulphates and selenates. It indicates the rotation, with increase of the
atomic weight of the metal, of the ellipsoid which graphically
represents the optical properties, about the unique axis of symmetry,
which is likewise an axis of optical symmetry, of the crystal. In the
potassium salt the ellipsoid occupies the position indicated by the
ellipse drawn in continuous line in Fig. 62, the section of the
ellipsoid by the symmetry plane; the outline of a tabular crystal
parallel to the symmetry plane is also given, as well as the axes of the
crystal and of the ellipsoid lying in that plane.
[Illustration:
FIG. 62.—Diagram illustrating Progressive Rotation of Optical
Ellipsoid in Monoclinic Isomorphous Series.
]
In the rubidium salt the ellipsoid has rotated over to the left, as
indicated by the dotted ellipse, for a few degrees, the number of which
varies slightly for the different groups of double salts; while in the
cæsium salt it has swung over much more still, to the place marked by
the ellipse drawn in broken line. In both this and the last illustration
it will be remarked that the optical change is greater between the
rubidium and cæsium salts than it is between the potassium and rubidium
salts, the reason being that the optical properties are usually
functions (of the atomic weight of the interchangeable elements) which
are of an order higher than the first corresponding to simple
proportionality.
These three ocular illustrations may serve to render this interesting
law of progression, according to the atomic weight of the
interchangeable elements which give rise to the isomorphous series,
clearer to the mind, by placing before it concrete instances of the
operation of the law.
The generalisation itself may be very concisely expressed in the
statement that:
_The whole of the properties, morphological and physical, of the
crystals of an isomorphous series of salts are functions of the atomic
weights of the interchangeable chemical elements of the same family
group which give rise to the series._
The fact that this law extends to the structural dimensions, equally
with all other morphological properties, as stated under (3) at the
beginning of this chapter, is of especial interest. For it has actually
been found possible to determine the relations of the dimensions of the
unit parallelepipeda of the space-lattices of the various salts, that
is, the separation of the molecular points of the space-lattice in the
directions of the three crystal axes, for the various salts of the
isomorphous series. This is achieved by combining in suitable formulæ
the volume of the unit cell of the space-lattice with the relative
lengths of the three crystal axes, _a_, _b_, _c_.
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