The axial ratios _a_ : _b_ : _c_ are calculated from the measurements of
the crystal angles, as explained in Chapter VI., page 68, and the volume
is the physical constant long known as “molecular volume,” but now for
the first time understood as regards its meaning in the case of solid
substances. It is the quotient of the chemical constant molecular weight
(the sum of the atomic weights, taking into account the number of atoms
of each element present) by the specific gravity of the substance, here
the solid crystal. Very great care has been taken to obtain absolutely
accurate determinations of the specific gravities of the salts, as much
depends on this now very valuable physical constant, and all the values
obtained were reduced to the constant reference temperature of 20°, as
the density notoriously alters rapidly with change of temperature.
We have thus arrived at morphological constants of very considerable
importance, which are best termed “_Molecular Distance Ratios_,” as they
express the relative distances apart in the three directions of space of
the centres of gravity or other representative points of contiguous
chemical molecules. They are dependent on three experimental
determinations, atomic weight, specific gravity, and crystal angles, all
of which have now been brought to the highest pitch of refinement and
accuracy; hence the molecular distance ratios are particularly
trustworthy constants. If it were only known how much is matter and how
much is space in the molecular parallelepipedal cell, we should actually
have in these constants a relative measure of the sizes of the
molecules. They do give us, however, the relative directional dimensions
of the molecular unit parallelepipedal cells of the space-lattices of
the various members of the isomorphous series, just as the molecular
volumes give us the relative volumes of these cells. For in an
isomorphous series we are absolutely sure that the plan on which the
space-lattice is constructed, its style of architecture, is identical
for all the members of the isomorphous series. Hence, the molecular
distance ratios are in these cases absolutely valid and strictly
comparable. The ratios are generally expressed by the Greek letters χ :
ψ : ω.
On comparing the molecular distance ratios for a potassium, a rubidium,
and a cæsium salt of any of the series of sulphates, selenates,
permanganates, perchlorates, double sulphates or double selenates
investigated, we invariably find that the values of χ, ψ, and ω for the
rubidium salt (rubidium having the intermediate atomic weight) lie
between the analogous sets of three values for the potassium and cæsium
salts respectively, in complete accordance with the law.
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