The yellow and red varieties of phosphorus may also be due to a similar
cause, the yellow variety, which forms excellent crystals, corresponding
to P_{4}, while the red variety may correspond to a molecule composed of
a different number of atoms than four.
Another view of the nature of polymorphism has lately been brought
forward by Lehmann, as the result of his remarkable experimental
discovery of “liquid crystals,” to which fuller reference will be made
in Chapter XVI. This new view is, however, but an amplification of the
foregoing explanation of polymorphism, indicating the possible mode in
which the stereometric position of the atoms in the molecule does
actually influence and even determine the particular homogeneous
structure which shall be erected, and explains why the temperature plays
such an important rôle. Lehmann’s theory is that any one definitely
stereometrically constituted chemical molecule can only display one
particular homogeneous structure and form of crystal, and that when at a
particular temperature the system or class of symmetry is altered, this
occurs because the stereometric arrangement of the atoms within the
molecule is altered, that is, a new form of molecule is produced, which
naturally gives rise to a new form of crystal. As far as the author
understands it, this does not mean an isomeric change from the chemical
point of view, the chemical compound remaining the same, but that the
stereometric positions of the atoms have been changed, without altering
their chemical attachments, but sufficiently to change the nature of the
point-system which they produce. A significant fact in support of this
view is that the molecules of the substances forming liquid crystals are
usually very complicated and extended ones, comprising a large number of
atoms, the molecules, in fact, corresponding in length with the long
names of the organic substances of which they are generally composed.
Lehmann’s work has certainly proved that the molecule is endowed
with more individuality than has hitherto been ascribed to it, and
he even shows that there is some ground for believing that his
liquid crystals are such because this directive orientative force
resident in the molecules themselves maintains them in their
mutually crystallographically orientated positions even in the
liquid state, which may be and sometimes is as mobile as water. It
thus appears that any general acceptance of Lehmann’s ideas will
only tend to amplify and further explain the nature of polymorphism
on the lines here laid down, the temperature of conversion of one
form into another being merely that at which either a different
homogeneous packing is possible, or that at which the stereometric
relations of the atoms in the molecule are so altered as to produce
a new form of point-system without forming a new chemical compound.
Public-domain text, read in full here on John Shaqi.
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