_Enantiomorphism of Crystalline Form and Optical Activity._ It has
already been stated that two supplementary forms which are similar but
not identical, the one being the inverse or mirror-image reflection of
the other, as a right-hand glove is to a left-hand one, are termed
“enantiomorphous.” Also it has been shown that all those crystal forms
which have no plane of symmetry, either of simple symmetry or
alternating symmetry (which is equivalent to saying that no centre of
symmetry is present in addition to no plane of symmetry), are
enantiomorphous, and that such forms belong to eleven specific classes.
It has further been shown that the introduction of this principle of
mirror-image symmetry or enantiomorphism into the conditions already
laid down by Bravais and Sohncke for a homogeneous structure, by von
Fedorow, Schönflies, and Barlow, enabled those investigators to derive
the remaining 165 of the 230 possible types of homogeneous structures
compatible with crystal structure, over and above the 65 already
established by Bravais and Sohncke, and thus to complete the geometry of
crystal structure, when the units of such structure are represented by
points. Sohncke subsequently accepted the new principle, and modified
his own theory so as to bring it into line with it. He exhibited some
disinclination, however, at first, to accept the idea—which is a part of
the assumption of the other three authors just referred to, and which
appears to be absolutely necessary to explain one or two of the most
complicated of the crystal classes—of the possibility of two
enantiomorphous kinds of molecule being present in the crystal of the
same single substance, the balancing of the two sets having the effect
of producing mirror-image symmetry of the whole crystal, that is, the
development of a plane of symmetry.
Now the whole subject is of deep interest, both physical and chemical as
well as crystallographical, inasmuch as it is precisely such substances
as show enantiomorphism,—and can thus exist in two forms, one of which
is the mirror-image of the other and not its identical counterpart, the
two being like a pair of gloves,—which are found to possess the property
of rotating the plane of polarised light and which are therefore said to
be “optically active.” Moreover, the property may be displayed by both
the crystals and their respective solutions, or by the crystals only.
If, therefore, two optical antipodes of the same substance are known,
one rotating the plane of polarisation to the right and the other
rotating it to the same extent to the left, their crystals invariably
exhibit mirror-image symmetry with respect to each other. The converse
does not necessarily hold good, however, that a crystal possessing the
symmetry of one of these eleven classes will always exhibit optical
activity.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account