We now know that the decomposable inactive variety, racemic acid, may
be readily obtained by· dissolving equal weights of the ordinary
dextro and lævo varieties in water and crystallising the solution by
slow evaporation at the ordinary temperature. For further
investigation has fully borne out the conclusion of Pasteur, that
racemic acid simply consists of a molecular compound of the two active
varieties. It is thus itself inactive because it is externally
compensated, the two kinds of enantiomorphous molecules being
alternately regularly distributed throughout the whole crystal
structure, the very case which von Fedorow, Schönflies, and Barlow
assumed to be possible, and which Sohncke only tardily admitted. The
crystalline form of racemic acid is, as was to be expected, quite
different from the monoclinic form of the active tartaric acids, being
triclinic; and indeed it is not crystallographically comparable with
the active form, inasmuch as the crystals of racemic acid contain a
molecule of water of crystallisation, whereas the active varieties
crystallise anhydrous.
Ordinary dextro and lævo tartaric acids crystallise in identical forms
of the sphenoidal or monoclinic-hemimorphic class of the monoclinic
system, the class which is only symmetrical about a digonal axis, the
unique symmetry plane of the monoclinic system, which also operates when
full monoclinic symmetry is developed, being absent in this class. Hence
the interfacial crystal angles, the monoclinic axial angle, and the
axial ratios are identical for the two varieties. But the crystals are
hemimorphic, owing to the absence of the symmetry plane, and
complementarily so, the dextro variety being distinguished by the
presence of only the right clino-prism {011}, while the lævo variety is
characterised by the presence only of the left-clino-prism {0̄11}, these
two complementary forms, each composed of only two faces and which on a
holohedral crystal exhibiting the full symmetry of the monoclinic system
would both be present as a single form of four faces, being never both
developed on the same optically active crystal.
This hemimorphism of the two kinds of crystals will be rendered clear by
Figs. 63 and 64, representing typical crystals of dextro and lævo
tartaric acids which are obviously the mirror images of each other.
[Illustration:
FIG. 63.
]
[Illustration:
FIG. 64.
Crystals of Dextro and Lævo Tartaric Acids.
]
A remarkable discovery was made by Pasteur in connection with one
of the salts of racemic acid, sodium ammonium racemate,
Na(NH_{4})C_{4}H_{4}O_{6}, or
COONH_{4}
|
CHOH
|
CHOH
|
COONa
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