This interesting pioneer case of tartaric acid has been the cause of
the term “racemic” being applied to the inactive form of a substance
when it is decomposable into two oppositely optically active
enantiomorphous varieties of the substance. No well authenticated
exception has been found, in all the many instances which have been
observed of the phenomenon since Pasteur’s time, to the fact that
optically active substances exhibit what was formerly termed
hemihedrism; that is, expressing the case in accordance with our later
more accurate ideas of crystal structure as elucidated in previous
chapters, such substances invariably belong to classes of symmetry
possessing less than the full number of elements of symmetry possible
to the system to which the class belongs. These classes are eleven in
number, those possessing no plane of symmetry; they are, namely, the
asymmetric class of the triclinic system, the sphenoidal class of the
monoclinic system (to which the two tartaric acids, dextro and lævo,
belong), the bisphenoidal class of the rhombic system, the pyramidal
and trapezohedral classes of the trigonal, tetragonal, and hexagonal
systems, and the tetrahedral-pentagonal-dodecahedral and
pentagonal-icositetrahedral classes of the cubic system.
The optical activity has been proved by Le Bel and Van t’Hoff to be due
in most cases to enantiomorphism of the chemical molecules, that is, to
the enantiomorphous stereometric arrangement of the atoms in the
molecules, and therefore also,—as we have just seen, in accordance with
the geometrical theory of crystal structure,—of the combined
point-system in the case of each of the two varieties.
The point-systems are probably of a spiral screw-like character, either
right-handed or left-handed, as has been shown by Sohncke to be the case
for the two varieties of quartz, which crystallises in the trapezohedral
class of the trigonal system, one of the eleven classes just enumerated.
The example afforded by quartz will be developed fully in the next two
chapters, as this beautifully crystallised mineral enables us to study
and to demonstrate the phenomena of optical activity in a unique manner
and on the large scale.
The solutions as well as the crystals are usually optically active in
the cases where, as in the instance of the tartaric acids, the
substances are soluble in water or other solvent. Occasionally, however,
the optical activity is lost by dissolving in a solvent, and in such
cases it is the point-system only, and not the molecules themselves,
which is enantiomorphous. Sodium chlorate, NaClO_{3}, is an instance of
this kind. Moreover, a crystal can belong, as already mentioned, to one
of the eleven above enumerated classes of symmetry without displaying
optical activity, as all the point-systems possessing the symmetry of
these eleven classes do not exhibit screw-coincidence movements. Barium
nitrate, Ba(NO_{3})_{2}, is such a case.
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