The two “optical antipodes,” as the dextro and lævo varieties are
conveniently termed, of an optically active substance thus possess an
enantiomorphous crystal structure; but they are alike in their physical
properties such as density, melting point, optical refraction and optic
axial angle, cleavage, and elasticity. The crystal angles are identical
for the forms which are developed in common by them, and which are
usually those which the particular low class of symmetry possesses in
common with the holohedral class of the system. The crystallographic
difference between the two varieties comes in with respect to the
specific forms characteristic of the particular class of lower than full
systematic symmetry, and these forms are never displayed in common by
the two varieties, this being the essence of the enantiomorphism. When
the crystals are not rich in faces, however, it frequently happens that
only the common forms of higher symmetry just referred to are developed
on the crystals, and the two varieties are then indistinguishable in
exterior configuration; it is only on testing their rotatory power,
either by means of a section-plate of the crystal or by means of a
solution, or their pyro-electric properties, or, lastly, their
etch-figures afforded by a trace of a solvent (which etchings on the
crystal faces are enantiomorphous and an excellent indication of the
true symmetry), that their real character can be ascertained. Many
mistakes have been made in the past, and crystals assigned to a higher
than their true class of symmetry, owing to the investigation of only a
single crop of crystals fortuitously poor in the number of forms
displayed.
In the racemic form, if one should be deposited from the mixed solutions
of the two optical antipodes as a molecular compound of the latter, we
have an occurrence akin to polymerism, that is, the combination into a
single whole entity of a number of molecules, essentially two in the
case of racemism. Just as polymeric varieties of organic substances are
always found to have quite different crystalline forms, so an optically
inactive racemic form of a substance is generally quite different
crystallographically to the dextro and lævo varieties. But there is
usually some similarity along specific zones of the crystals, a kind of
isogonism or morphotropy being developed, such as has been shown to
occur, for instance, by Armstrong and Pope in the case of the substance
sobrerol.[13]
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