"And that which is true of water is true, in a greater or less degree, of
other products of combustion. The burning of charcoal produces carbonic
acid, and carbonic acid will not burn because it is the production of
combustion. A candle is extinguished by it as quickly as by water. By a
recent invention carbonic acid is used to extinguish conflagrations. The
carbon has once united with oxygen, and a second combination with an
additional amount, or, as a chemist would say, with another equivalent, of
oxygen is much more difficult."
"I think," said Samuel, "I now understand why water will not burn, but
will you please also to tell us why water puts out fire better than
almost anything else?"
"In order to extinguish fire one of two things must be done: either the
supply of oxygen must be cut off or the combustible must be cooled down to
a temperature below the burning point, when the combustion will cease of
itself. When we shut the draught of an air-tight stove, we check the
combustion by shutting off the full supply of oxygen. If we could wholly
prevent the access of oxygen to the fuel, the fire would at once be
extinguished. If oxygen should then be admitted again before the fuel had
cooled down below the burning point, combustion would at once begin again.
A blazing brand is extinguished by being thrust into ashes, because it is
shut away from oxygen. In the same way we extinguish the flame of a candle
with a tin extinguisher. On the other hand, fires often go out because the
necessary temperature is not maintained. Water puts out fire in both these
ways, but especially by the second. Water poured in torrents from a fire
engine upon a fire forms a film of water, and the burning material shuts
out the oxygen. But the water acts chiefly by lowering the temperature.
No other known substance except hydrogen gas requires so much heat to
raise it through a given number of degrees of temperature as water. As
much heat is required to heat one pound of water as thirty pounds of
mercury. Hence, water poured upon burning timber cools it to so low a
temperature that it ceases to burn.
Public-domain text, read in full here on John Shaqi.
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