The ash left after burning a diamond invariably contains iron as
its chief constituent; and the most common colours of diamonds,
when not perfectly pellucid, show various shades of brown and
yellow, from the palest “off colour” to almost black. These
variations give support to the theory advanced by Moissan that
the diamond has separated from molten iron--a theory of which I
shall say more presently--and also explain how it happens that
stones from different mines, and even from different parts of the
same mine, differ from each other. Further confirmation is given
by the fact that the country round Kimberley is remarkable for
its ferruginous character, and iron-saturated soil is popularly
regarded as one of the indications of the near presence of diamonds.
GRAPHITE
Intermediate between soft carbon and diamond come the graphites.
The name graphite is given to a variety of carbon, generally
crystalline, which in an oxidising mixture of chlorate of potassium
and nitric acid forms graphitic oxide. This varies in colour
from green to brown or yellow, or it is almost without colour,
according to the completeness of the reaction. Graphites are of
varying densities, from 2·0 to 3·0, and generally of crystalline
aspect. Graphite and diamond pass insensibly into one another. Hard
graphite and soft diamond are near the same specific gravity. The
difference appears to be one of pressure at the time of formation.
Some forms of graphite exhibit the remarkable property by which
it is possible to ascertain approximately the temperature at
which they were formed, or to which they have subsequently been
exposed. Sprouting graphite is a form, frequently met with in
nature, which on moderate heating swells up to a bulky, very
light mass of amorphous carbon. Moissan has found it in blue
ground from Kimberley; my own results verify his. When obtained by
simple elevation of temperature in the arc or the electric furnace
graphites do not sprout; but when they are formed by dissolving
carbon in a metal at a high temperature and then allowing the
graphite to separate out on cooling, the sprouting variety appears.
The phenomenon of sprouting is easily shown. If a few grains are
placed in a test-tube and heated to about 170° C., the grains
increase enormously in bulk and fill the tube with a light form of
amorphous carbon.
The resistance of a graphite to oxidising agents is greater the
higher the temperature to which it has previously been exposed.
Graphites which are easily attacked by a mixture of fuming nitric
acid and potassium chlorate are rendered more resistant by strong
heat in the electric furnace.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account