Until recent years carbon was considered absolutely non-volatile
and infusible; but the enormous temperatures placed at the disposal
of experimentalists by the introduction of electricity show
that, instead of breaking rules, carbon obeys the same laws that
govern other bodies. It volatilises at the ordinary pressure at a
temperature of about 3600° C., and passes from the solid to the
gaseous state without liquefying. It has been found that other
bodies, such as arsenic, which volatilise without liquefying at
the ordinary pressure, will easily liquefy if pressure is added to
temperature. It naturally follows that if along with the requisite
temperature sufficient pressure is applied, liquefaction of carbon
will take place, when on cooling it will crystallise. But carbon at
high temperatures is a most energetic chemical agent, and if it can
get hold of oxygen from the atmosphere or any compound containing
it, it will oxidise and fly off in the form of carbonic acid. Heat
and pressure therefore are of no avail unless the carbon can be
kept inert.
It has long been known that iron, when melted, dissolves carbon,
and on cooling liberates it in the form of graphite. Moissan
discovered that several other metals, especially silver, have
similar properties; but iron is the best solvent for carbon. The
quantity of carbon entering into solution increases with the
temperature.
[Illustration: FIG. 20. MOISSAN’S ELECTRIC FURNACE.
To face p. 116.]
For the artificial manufacture of diamond the first necessity is
to select pure iron--free from sulphur, silicon, phosphorus,
etc.--and to pack it in a carbon crucible with pure charcoal from
sugar. The crucible is then put into the body of the electric
furnace and a powerful arc formed close above it between carbon
poles, utilising a current of 700 ampères at 40 volts pressure
(Fig. 20). The iron rapidly melts and saturates itself with carbon.
After a few minutes’ heating to a temperature above 4000° C.--a
temperature at which the iron melts like wax and volatilises in
clouds--the current is stopped and the dazzling fiery crucible is
plunged beneath the surface of cold water, where it is held till
it sinks below a red heat. As is well known, iron increases in
volume at the moment of passing from the liquid to the solid state.
The sudden cooling solidifies the outer layer of iron and holds
the inner molten mass in a tight grip. The expansion of the inner
liquid on solidifying produces an enormous pressure, and under the
stress of this pressure the dissolved carbon separates out in
transparent forms--minutely microscopic, it is true--all the same
veritable diamonds, with crystalline form and appearance, colour,
hardness, and action on light, the same as the natural gem.
Public-domain text, read in full here on John Shaqi.
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