+34. Third Experiment.+--(_a._) I dissolved in _aqua fortis_ the white
magnesia employed in medicine; I evaporated this solution to dryness. I
then placed the salt in a small retort for distillation, as is described
in § 32. Even before the retort was red hot the acid of nitre separated
from the magnesia, and that in blood-red vapours; and at the same moment
the bladder began to expand. The air thus obtained was my fire-air.
It is thus seen constantly that the acid of nitre goes off again
blood-red when separated by means of heat from the metals which had been
dissolved in this menstruum.
(_b._) I distilled mercurial nitre in the foregoing manner until the
acid of nitre had separated from the residual red precipitate. In this
case also I obtained our fire-air.... Whence comes the boiling of nitre,
fused in a crucible and obscurely red-hot? Neither smoke nor vapours are
seen to rise from it, and yet coal dust flying above the open crucible
takes fire, burning brilliantly. Whence comes it that such nitre
maintained in red-hot fusion in a glass retort for half an hour, becomes
moist in open air and deliquesces after cooling, and still does not
show any trace of alkali? (§ 27, letter _c._) What is the reason that
this liquefied nitre permits its volatile acid to escape immediately,
when rubbed or mixed with the vegetable acids?... If the chemists of the
preceding century had thought worthy of a more particular examination,
the elastic fluids resembling air which manifest themselves in so many
operations, how advanced should we now be! They desired to see
everything in corporeal form, and to collect everything as drops in the
receiver. This is now for the first time better inquired into, and the
air has begun to be carefully examined: and who is there who does not
perceive the advantage which the results of such experiments carry with
them?
* * * * *
+35. Fourth Experiment.+--I put an ounce of purified nitre into a glass
retort for distillation and made use of a bladder, moistened and emptied
of air, in place of a receiver (Fig. 3). As soon as the nitre began to
glow it also began to boil, and at the same time the bladder was
expanded by the air that passed over. I proceeded with the distillation
until the boiling in the retort ceased, and the nitre was about to force
its way through the softened retort. I obtained in the bladder the pure
fire-air which occupied the space of 50 ounces of water. This is the
cheapest and best method of obtaining fire-air.
* * * * *
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