Dyes and dyeingPellew, Charles E. (Charles Ernest), Viscount Exmouth
Science
Dyes and dyeing
Pellew, Charles E. (Charles Ernest), Viscount Exmouth
Dyes and dyeing
The lime compound, which contains more chlorine than the others, and
has the great advantage of being dry, has long been known as chloride
of lime or as bleaching powder, and has been, and is, commonly
used from one end of the world to the other as a quick, ready,
cheap source of chlorine either for bleaching or for disinfection.
The potash and soda compounds, known respectively as Labarraque’s
solution and Javelle water, are less active and powerful than
bleaching powder, but have the same general properties.
Over a hundred years ago, very soon after the discovery of the
bleaching properties of these compounds, chemists began to use them,
not only for decolorizing and whitening raw cotton and linen cloth,
but also for discharging the color in patterns from dyed goods. The
process was not a difficult one, and is used to this day to some
extent in the calico printing mills. The cloth is first dyed to
shade, fixed, and dried. The pattern is then printed on with a paste
containing some solid organic acid, like citric acid or tartaric
acid, dissolved in it. After drying, the printed cloth is passed
through a bath of bleaching powder in water, possibly with a little
weak alkali added, to be sure that no free chlorine is present;
and wherever the bleaching powder meets the acid the cloth is
decolorized, but the rest of the cloth comes out of the bath without
being much, if at all, altered in color. Of course, on coming out
of this bath the cloth must be thoroughly washed to get rid of any
traces of chloride of lime, which otherwise, on exposure to the air,
would play havoc with the rest of the colors.
This process worked very well with the old vegetable dyes, and,
every now and then, some craftsman, of an experimental turn of mind,
revives it for stencil work. The dyed cloth is stencilled with a
paste made of wheat flour boiled with a saturated solution of citric
acid, it is dried, and then passed through a bath of bleaching
powder in water, say two or three tablespoonfuls to the gallon. It
is generally best to stir in a few drops of a soda solution to the
bath, till all smell of chlorine has gone, or else the background may
be affected. The stencilled cloth is dipped in this bath, and kept
there for a few minutes, until the bleaching process is well under
way, and then taken out, and washed in hot soap and water, and rinsed
well.
_Advantages and Disadvantages of Bleaching Powder Discharge._—The
chief advantage of this process is that it is very cheap and the
materials can be bought at almost any grocery. The disadvantages are,
however, important. As long as it is confined to easily discharged,
comparatively fugitive, colors, it will destroy the color all right
in the stencilled parts, although the bleaching powder bath is apt
to attack the color in the body of the cloth, and the outlines of
the pattern are apt to be soft and irregular because of the escaping
chlorine, where the citric acid is acting.
Public-domain text, read in full here on John Shaqi.
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