Dyes and dyeingPellew, Charles E. (Charles Ernest), Viscount Exmouth
Science
Dyes and dyeing
Pellew, Charles E. (Charles Ernest), Viscount Exmouth
Dyes and dyeing
When, however, very fast dyes are being used, as for instance, the
Vat colors or, indeed, a great many of the best dyes in all the
classes, the action of chlorine is very slow, and slight, and, in
order to really destroy the color both the acid and the bleaching
powder will often have to be so strong that the chlorine set free
will destroy the fibre as well. For the term “fastness to light”
implies, as a rule, fastness also to oxidation in general, and dyes
like the best modern ones which will let the cloth rot away from
under them, when long exposed to the weather without changing color,
are very apt also to keep their color, even when the cloth is _burnt_
away from under them by the action of chlorine.
Accordingly, this process is distinctly one that needs careful
experimentation before it is tried on any important piece of work.
There are plenty of dyestuffs among the Salt colors, and also among
the Sulphur colors, which discharge well with chlorine. And the
calico printer, working, as he generally does to this day, with
comparatively fugitive dyes, and weighing accurately both acid and
bleaching powder, can generally get good results with it. But there
is always the disadvantage, that the least excess of chlorine will
attack and tender the cloth, and the better the dyestuff, as a rule,
the stronger the oxidizing agent must be to discharge it.
(b) _Discharge by Reduction, Hydrosulphite, etc._—The wary craftsman
will find the process much less dangerous to the cloth, and not much
more difficult, if instead of trying to _oxidize_ the dyestuff, he
attempts to discharge it by _reducing_ it; or, in other words, if
instead of trying to burn it out, he tries to take the oxygen away
from it.
It so happens that in a vast majority of cases a dyestuff becomes
decolorized by reducing it, just as well as by oxidizing it. There
is, however, a difference. When the color is oxidized, it is burnt up
and destroyed forever. When it is reduced, however, it is, in many
cases, only decolorized and not destroyed; and on standing in the air
it is apt to take up oxygen again, and to regain some, at least, of
the original color. On the other hand, while any oxidation process is
liable to attack the cloth as well as the color, the reducing agents
now in use have no effect upon the materials, even when powerful
enough to act on the very fastest dyestuffs.
As before mentioned, the most satisfactory reducing agent at present
known to dyers is hydrosulphite of soda, and this can be incorporated
in a paste, and used for discharge stencilling. It is, however, as a
rule, more satisfactory to use the more expensive, but more permanent
hydrosulphite compound, described, in the last chapter, as acting
only when heated.
The reducing stencil paste can be easily made by mixing with some
“gum dragon” or flour paste, as much as it will hold of a saturated
solution of the “Stencil Salt.”
Public-domain text, read in full here on John Shaqi.
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