In our chapter on the accumulator or storage cell we saw that a current
of electricity has the power of decomposing certain liquids; that
is to say, it is able to split them up into their component parts.
This power has given rise to the important art of electroplating and
electrotyping. Electroplating is the process of depositing a coating
of a rarer metal, such as gold, silver, or nickel, upon the surface of
baser or commoner metals; and electrotyping is the copying of casts,
medals, types, and other similar objects. The fact that metals could
be deposited by the decomposition of a solution by a current was known
in the early days of the voltaic cell, but no one seems to have paid
much attention to it. An Italian chemist published in 1805 an account
of his success in coating two silver medals with gold, and some thirty
years later Bessemer transformed lead castings into fairly presentable
ornaments by coating them with copper, but commercial electroplating
may be said to have begun about 1840, when an Englishman named
Elkington took out a patent for the process. Since then the processes
of electroplating and electrotyping have rapidly come more and more
into use, until to-day they are practised on a vast scale, giving
employment to thousands.
Electroplating on a small scale is a very simple affair. A solution
of the metal which it is desired to deposit is placed in a suitable
vessel. Two metal rods are placed across the top of this vessel, and
from one of these is suspended a plate of the same metal as that in
the solution, and from the other is hung the article to receive the
coating. The positive terminal of a voltaic battery is connected to
the rod supporting the plate, and the negative terminal to the rod
carrying the article to be plated. As the current passes through the
solution from the plate to the article the solution is decomposed, and
the article receives a coating of metal. The solution through which the
current passes, and which is decomposed, is called the _electrolyte_,
and the terminal points at which the current enters and leaves the
solution are called _electrodes_. The electrode by which the current
enters the electrolyte is called the _anode_, and the one by which it
leaves is called the _cathode_.
Public-domain text, read in full here on John Shaqi.
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