If we wish to deposit a coating of copper on, say, an old spoon which
has been dismissed from household service, a solution of sulphate
of copper must be made up and placed in a glass or stoneware jar.
Two little rods of brass, copper, or any other good conductor are
placed across the jar, one at each side, and by means of hooks of
wire a plate of copper is hung from one rod and the spoon from the
other. The positive terminal of a battery of Daniell cells is then
connected to the anode rod which supports the copper plate, and the
negative terminal to the cathode rod carrying the spoon. The current
now commences its task of splitting up the copper-sulphate solution
into pure copper and sulphuric acid, and depositing this copper upon
the spoon. The latter is very quickly covered with a sort of “blush”
copper, and the coating grows thicker and thicker as long as the
current is kept at work. If there were no copper plate forming the
anode the process would soon come to a standstill, on account of the
copper in the electrolyte becoming used up; but as it is the sulphuric
acid separated out of the electrolyte takes copper from the plate and
combines with it to form a further supply of copper sulphate. In this
way the strength of the solution is kept up, and the copper anode
becomes smaller and smaller as the coating on the spoon increases
in thickness. It is not necessary that the anode should consist of
absolutely pure copper, because any impurities will be precipitated to
the bottom or mixed with the solution, nothing but quite pure copper
being deposited on the spoon. At the same time if the copper anode
is very impure the electrolyte quickly becomes foul, and has to be
purified or replaced by new solution.
[Illustration:
_By permission of_] [_W. Canning & Co._
FIG. 35.--Small Electroplating Outfit.]
To nickel-plate the spoon we should require a nickel plate for the
anode and a nickel solution; to silver-plate it, a silver anode and
solution, and so on. Fig. 35 shows at simple but effective arrangement
for amateur electroplating in a small way.
Public-domain text, read in full here on John Shaqi.
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