Electrotyping is practically the same as electroplating, except that
the coating is removed from the support on which it is deposited.
The process is largely used for copying engraved plates for printing
purposes. The plate is first rubbed over with a very weak solution
of beeswax in turpentine, to prevent the deposit from adhering to it,
and it is then placed in a copperplating vat and given a good thick
coating. The coating is then stripped off, and in this way a reversed
copy of the plate is obtained. This copy is then replaced in the vat,
and a coating of copper deposited upon it, and this coating, when
stripped off, forms an exact reproduction of the original, with every
detail faithfully preserved. An engraved plate may be copied also by
making from it a mould of plaster or composition. The surface of this
mould is then rendered conducting by sprinkling over it a quantity of
plumbago, which is well brushed into all the recesses, and a coating
of copper deposited on it. As the mould was a reversed copy of the
original, the coating formed upon it is of course an exact copy of the
plate. If the copy has to be made very quickly a preliminary deposit
of copper is chemically formed on the mould before it is placed in the
vat. This is done by pouring on to the mould a solution of sulphate of
copper, and sprinkling iron filings over the surface. The filings are
then brushed down on to the face of the mould with a fine brush, and a
chemical reaction takes place, resulting in the precipitation of copper
from the solution. After the filings have been washed away, the mould
is placed in the vat, and the deposition of copper takes place very
rapidly.
Engraved copperplates are often nickel or steel-plated to give their
surface greater hardness, so that the printer may obtain a larger
number of sharp impressions from the same plate. Stereotypes also are
coated with nickel for a similar reason.
Before the dynamo came into general use all electroplating and
electrotyping was done with current supplied by voltaic cells, and
though the dynamo is now used exclusively in large plating works,
voltaic cells are still employed for work on a very small scale. A
cell which quickly polarizes is quite useless for plating purposes,
and one giving a constant and ample supply of current is required. The
Daniell cell, which was described in Chapter IV., is used, and so also
is the Bunsen cell, which consists of a porous pot containing strong
nitric acid and a carbon rod, placed in an outer stoneware vessel
containing dilute sulphuric acid and a zinc plate. The drawback to
this cell is that it gives off very unpleasant fumes. The dynamos used
for plating work are specially constructed to give a large amount of
current at very low pressure. Continuous current only can be used, for
alternating current would undo the work as fast as it was done, making
the article alternately a cathode and an anode.
CHAPTER XXIII
INDUSTRIAL ELECTROLYSIS
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