The metal copper, as obtained from copper ore, contains many impurities
of various kinds. For most purposes these impurities greatly affect the
value of the copper, and before the metal can be of much commercial
use they must be got rid of in some way. In the previous chapter, in
describing how to copperplate an old spoon, we saw that the anode need
not consist of pure copper, because in any case nothing but the pure
metal would be deposited upon the spoon. This fact forms the basis of
the important industry of electrolytic copper refining. The process is
exactly the same as ordinary copperplating, except that the cathode
always consists of absolutely pure copper. This is generally in the
form of a sheet no thicker than thin paper, but sometimes a number of
suspended wires are used instead. A solution of copper sulphate is used
as usual for the electrolyte, and the anode is a thick cast plate of
the impure copper. The result of passing a current through the solution
is that copper is taken from the anode and carried to the cathode, the
impurities falling to the bottom of the vat and accumulating as a sort
of slime. In this way thick slabs of pure copper are obtained, ready to
be melted down and cast into ingots.
The impurities in the raw copper vary according to the ore from which
it is obtained, and sometimes gold and silver are found amongst them.
When the copper is known to contain these metals the deposit at the
bottom of the refining vats is carefully collected, and from it a
considerable quantity of gold and silver is recovered. It is estimated
that about half a million tons of copper are refined every year. An
immense amount of this pure copper is used for electrical purposes, for
making conducting wires and cables, and innumerable parts of electric
appliances and machinery of all kinds; in fact it is calculated that
more than half of the copper produced all over the world is used in
this way.
A similar method is employed to obtain the precious metals in a pure
state, from the substance known as “bullion”; which consists usually of
an intermingling of gold, silver, and copper, with perhaps also lead.
Just as in copper refining, the raw material is used as the anode, and
a strip of pure gold or silver, according to which metal is required,
as the cathode. A silver solution is used if silver is wanted, and a
gold solution if gold is to be deposited.
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